<P><B>Abstract</B></P> <P>The development of a novel accelerator capable of simultaneously enhancing the cross-linking density and ductility of an epoxy resin without sacrificing the reaction rate is reported. The basic ...
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https://www.riss.kr/link?id=A107465854
2019
-
SCI,SCIE,SCOPUS
학술저널
303-311(9쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<P><B>Abstract</B></P> <P>The development of a novel accelerator capable of simultaneously enhancing the cross-linking density and ductility of an epoxy resin without sacrificing the reaction rate is reported. The basic ...
<P><B>Abstract</B></P> <P>The development of a novel accelerator capable of simultaneously enhancing the cross-linking density and ductility of an epoxy resin without sacrificing the reaction rate is reported. The basic concept comprises the synthesis of a tertiary amine-functionalized polyrotaxane (PRX_NR1) accelerator: a molecular necklace structure that induces a high cross-linking density as well as active molecular movement. Fourier transform infrared spectroscopy and differential scanning calorimetry measurements confirmed that the PRX_NR1-containing epoxy resin afforded a high reaction rate. Furthermore, the cross-linking density and mechanical properties of the epoxy resin were confirmed by dynamic mechanical analysis and tensile testing. Consequently, the PRX_NR1-containing epoxy resin greatly increased the cross-linking density, thereby resulting in an increase in tensile strength and glass transition temperature. Interestingly, the epoxy resin exhibited a simultaneous increase in ductility which is important to avoid brittle fracture (low toughness) of the epoxy resins. These results indicate that the proposed molecular necklace-like supramolecular PRX_NR1 accelerator is highly effective to overcome the traditional drawbacks of an epoxy resin that pose significant problems in the industrial field.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Molecular necklace-like supramolecular accelerator for epoxy resin was suggested. </LI> <LI> The synthesized accelerator displayed fast room temperature curing rate. </LI> <LI> The cross-linking density and ductility was simultaneously enhanced. </LI> </UL> </P>