Ionene copolymer electrolyte obtained from cyclo-addition of di-alkyne and di-azide monomers for solid-state smart glass windows

다국어 초록 (Multilingual Abstract)

A copoly(ionic liquid) (coPIL) based on 1,2,3-triazolium bearing trioxyethylene and tetraoxyethylenespacers was successfully synthesized as electrolyte for all-solid state electrochromic devices (ECD). Thispolyelectrolyte was produced by reacting triethylene glycol (TEG3)-diazide and tetraethylene glycol(TEG4)-dialkyne monomers through a ‘click’ reaction, copper-catalyzed alkyne-azidecycloadditon(CuAAC), and subsequently underwent several alkylation and anion metathesis. The new coPIL bearingethylene glycol fragments exhibited excellent thermal degradation temperature (Td10 = 230 C) and ionicconductivity (s = 8.8

10 5 S cm 1) which resulted to an efficient color switching (tc = 11.8 s andtb = 6.2 s), a high optical contrast (DT = 24%) and a remarkable stability (after 3000 cycles) of a symmetricall-solid-state smart glass window. The structural design of this new polyelectrolyte material and itscorresponding properties make it an excellent electrolyte for many electrochemical devices that requirezero electrolyte leakage.

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