고분자 전해질 연료전지용 부분 공유 가교된 술폰화 폴리아릴렌에테르술폰 막의 제조 및 특성

국문 초록 (Abstract)

술폰화 폴리아릴렌에테르술폰 공중합체를 직접 중합법으로 합성하고 공유 가교하여 연료전지용 고분자 전해질 막을 제조하였다. 최적의 전해질 막 제조를 위하여 가교제의농도를 30~90 v/v% 및 가교시간을 30분 내지 720분의 범위에서 다양한 조성의 전해질 막 제조실험이 수행되었으며 FT-IR분광법 및 열 중량분석, 수소 이온 전도도 측정 등을 통해 전해질 막의 기본 특성들을 평가하였다. 수소 이온 전도도는 가교도에 따라 감소하는 것으로 나타났으며, 물 흡수율 및 메탄올 투과도도 함께 낮아짐을 알 수 있었다.

다국어 초록 (Multilingual Abstract)

Covalent-crosslinked sulfonated poly(arylene ether sulfone) (SPAES) copolymers were synthesized copolymerization technique and additionally crosslinked with divinylbenzene (DVB). To optimize the reaction condition, a concentration of crosslinking agent and a reaction time were varied in the ranges of 30~90 v/v% and 30~720 min. The properties of the crosslinked membranes were investigated by SEM, TGA and the measurement of proton conductivity. It was found that the proton conductivity of crosslinked membranes decreased depending on a degree of crosslinking while water uptake and methanol permeability reduced.

참고문헌 (Reference)

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