Environmental and safety aspects of tertiary amino-functionalized ILs’ use as efficient recyclable catalysts for direct a-bromination of cyclic conjugated enones

다국어 초록 (Multilingual Abstract)

To develop chemical processes, according to Green Chemistry and Engineering principles, the use ofsolvents must be greatly reduced or eliminated. This paper focuses on the use of a new generation ofamino-functionalised ionic liquids, which enclose both solvent and catalytic properties for thebromination of cycloenones characterised by a conjugative endo-cyclic C¼C bond of various nature.
These procedures represent an interesting approach to the environmental sustainability of brominationreactions, even if liquid Br2 is toxic and awkward. Given the large uses of brominated compounds inchemical industry, this procedure could be specially appreciated.

참고문헌 (Reference)

1 P.T. Anastas, 37 (37): 94A-, 2003

2 E. De Rademaeker, 92 (92): 280-, 2014

3 L. Kuma, 50 (50): 705-, 2011

4 K. Tanaka, 1 : 3069-, 1999

5 J. Salazar, 1318-, 2004

6 V. Kavala, 70 (70): 4267-, 2005

7 M.P. Kaushik, 45B : 2542-, 2006

8 G. W. Kabalka, 28 : 925-, 1998

9 H. A. Muathen, 34 : 3545-, 2004

10 G. K. Dewkar, 5 (5): 4501-, 2003

11 C. Ye, 69 (69): 8561-, 2004

12 D. C. Braddock, 3 : 461-, 2004

13 T. K. Ying, 12 : 806-, 2004

14 K.M. Kim, 2641-, 2004

15 T. Moriuchi, 48 : 2667-, 2007

16 M. Eissen, 14 : 9830-, 2008

17 L. C. Mc Kenzie, 82 (82): 306-, 2005

18 P. Primerano, 54 : 4061-, 2013

19 P. Primerano, 91 (91): 1274-, 2016

20 P. Primerano, 43 : 2275-, 2015

21 R. H. Seevers, 82 (82): 575-, 1982

22 A. Butler, 93 (93): 1937-, 1993

23 G. W. Gribble, 28 : 335-, 1999

24 M. Kuroboshi, 68 (68): 3938-, 2003

25 Q. Yao, 68 (68): 7528-, 2003

26 C. Gao, 1444-, 2003

27 L. Euzenat, 2280-, 2003

28 M. M. Heravi, 46 (46): 8959-, 2005

29 T. Verdelet, 67 (67): 8757-, 2011

30 M. Alaee, 29 : 683-, 2003

31 G. Arsenault, 72 : 1163-, 2008

32 A. Covaci, 37 : 532-, 2011

33 P. L. Andersson, 25 : 1275-, 2006

34 D. T. Belmont, 50 (50): 4102-, 1985

35 G. Bose, 30 (30): 290-, 2001

36 D. Jyothi, 39 (39): 875-, 2009

37 A. A. Ponaras, 51 (51): 4741-, 1986

38 G. L. Dunn, 33 (33): 1454-, 1968

39 C. G. M. Janssen, 5 : 389-, 1982

40 K. M. Kim, 16 : 2641-, 2004

41 C. Shih, 45 : 4462-, 1980

42 W. Li, 9 : 4607-, 2007

43 G. V. Ramanarayanan, 12 : 2059-, 2002

44 E. J. Corey, 76 (76): 175-, 1954

45 R. E. Leard, 20 : 1363-, 1983

46 T. M. Harris, 35 : 1329-, 1970

47 M. Chia, 135 : 5699-, 2013

48 T. Maji, 76 (76): 736-, 2011

49 A. Merle, 12 (12): 981-, 1975

50 F. Zaragoza, 48 (48): 306-, 2005

51 H. Balli, 53 (53): 1903-, 1970

52 M. K. Chaudhuri, 39 : 8163-, 1998

53 M. Grignon-Dubois, 25 (25): 2999-, 1995

54 D. J. Cook, 26 : 4949-, 1961

55 S. J. Calvin, 16 : 82-, 2012

56 D. Jyothi, 14 : 2309-, 2009

57 E. Eder, 88 : 99-, 1990

58 D. Lutz, 93 : 305-, 1982

59 A. K. Basu, 44 : 2848-, 1984

60 L. Marnett, 148 : 25-, 1985

61 J. F. Brennecke, 47 : 2384-, 2001

62 K. M. Docherty, 7 : 185-, 2005

63 S. J. Patel, 23 : 483-, 2010

64 L. Kumar, 51 (51): 2227-, 2012

65 K.R. Olson, "Poisoning & Drug Overdose" Appleton & Lange 140-, 2003

66 A. Dicks, "Green chemistry metrics, A Guide to Determining and Evaluating Process Greenness" Springer International Publishing AG 2014

67 D.T. Allen, "Green Engineering" Prentice Hall 2002

68 R. Sheldon, "Green Chemistry in Pharmaceutical Industry" Wiley 1-, 2010

69 P. T. Anastas, "Green Chemistry Theory and Practice" Oxford University Press 1998

70 M.B. Smith, "Advanced Organic Chemistry, Reactions, Reactions, Mechanisms, and Structure" Wiley Interscience 2001