A comprehensive parametric study for solid-state lithium-ion battery through finite element simulation

다국어 초록 (Multilingual Abstract)

Solid-state lithium-ion batteries (SSB) have been regarded over recent years as a promising candidate for next-generationenergy storage due to their increased energy density and safety compared to conventional lithium-ion batteries. However,some internal and design parameter eff ects are yet to be fully comprehended. Since numerical modeling gives the opportunityto explore easily the various parameters and their eff ect on the performance of the cell, herein, we present a numericalmodel to study some parameters to optimize the performance of the SSB. The model considers diff usion of lithium-ion inboth the electrode and electrolyte and electrochemical reactions within the SSB. The model prediction agrees with someexperimental discharge profi les, which therefore validates the model. The model is then used to understand the role of theelectrode and electrolyte thickness and maximum concentration of lithium in the solid phase on the performance of thecell. It was observed that increasing cathode thickness increases the cell capacity, whereas reducing electrolyte thicknessimproves the capacity of the cell. Moreover, a direct proportionality is established between the maximum concentration oflithium and the call capacity. Additionally, the role of transport parameter, diff usivity, on the capacity of the SSB at diff erentdischarging rates is also studied. The understanding garnered from the study will improve the cell electrode design tailoredto the desired applications of the SSB.

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