<B>Graphic Abstract</B> <P>Lights, spectrometer, action: Crucial information about the detailed shape of the potential-energy surface in the vicinity of the transition state is obtained from the Fano resonances in the photodissoci...
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https://www.riss.kr/link?id=A107573869
2010
-
SCIE,SCOPUS
학술저널
1244-1247(4쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<B>Graphic Abstract</B> <P>Lights, spectrometer, action: Crucial information about the detailed shape of the potential-energy surface in the vicinity of the transition state is obtained from the Fano resonances in the photodissoci...
<B>Graphic Abstract</B>
<P>Lights, spectrometer, action: Crucial information about the detailed shape of the potential-energy surface in the vicinity of the transition state is obtained from the Fano resonances in the photodissociation cross-section of diazirine in the S<SUB>1</SUB> state. The excitation along the asymmetric C&n.bond;N stretching mode accelerates the ring-opening reaction, suggesting that two C&n.bond;N bonds of the excited diazirine break in a stepwise manner (see scheme).
<img src='wiley_img_2010/14337851-2010-49-7-ANIE200905619-content.gif' alt='wiley_img_2010/14337851-2010-49-7-ANIE200905619-content'>
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