Relevant properties for catalytic activity of sulfonic ion-exchange resins in etherification of isobutene with linear primary alcohols

다국어 초록 (Multilingual Abstract)

The catalyzed liquid-phase reaction of isobutene with a homologous series of linear alcohols, frommethanol to 1-butanol, has been studied at 333 K and 1.5 MPa. Sixteen sulfonic ion-exchange resins, tocover a wide range of properties, have been assayed. A response surface methodology analysis allowed toidentify the most relevant catalyst properties, and the change of their relative importance along thehomologous series of alcohols. Globally, reaction rates increase with the alcohol length. Resins with ahigh acid capacity and low specific volume of swollen polymer are the most active ones for the studiedetherification reactions.

참고문헌 (Reference)

1 J. Snelling, 56 : 1484-, 2006

2 J. H. Badia, 58 : 919-, 2015

3 M. A. Pérez, 482 : 38-, 2014

4 W. Piel, 39 : 273-, 1994

5 U. Grömping, 17 : 1-, 2006

6 M. A. Harmer, 221 : 45-, 2001

7 M. Umar, 64 : 4424-, 2009

8 K. Jerábek, 57 : 1595-, 1985

9 K. Jerábek, 57 : 1598-, 1985

10 B. Corain, 177 : 3-, 2001

11 M. A. Tejero, 517 : 56-, 2016

12 R. Bringué, 304 : 7-, 2013

13 J. Guilera, 413–414 : 21-, 2012

14 C. Casas, 396 : 129-, 2011

15 T. Tsuchida, 45 : 8634-, 2006

16 P. H. Pfromm, 34 : 515-, 2010

17 F. Ancillotti, 46 : 49-, 1977

18 R. S. Karinen, 76 : 81-, 2001

19 L. K. Rihko, 39 : 700-, 1994

20 C. Gómez, 36 : 4756-, 1997

21 J. A. Linnekoski, 174 : 1-, 1998

22 L. Solà, 36 : 2012-, 1997

23 J. Guilera, 78 : 14-, 2014

24 G. J. Hatchings, 15 : 23-, 1992

25 J. L. Nocca, 4 : 18-, 1994

26 C. Aellig, 5 : 1737-, 2012

27 M. Iborra, 39 : 1416-, 2000

28 F. Cunill, 32 : 564-, 1993

29 J. F. Izquierdo, 33 : 2830-, 1994

30 M. Iborra, 41 : 5359-, 2002

31 C. Fité, 169 : 165-, 1998

32 J. Tejero, 134 : 21-, 1996

33 J. Hidalgo, 12 : 1-, 2014

34 M. Vila, 117 : L99-, 1994

35 J. Tejero, 33 : 201-, 1997

36 J. H. Badia, 468 : 384-, 2013

37 E. W. de Menezes, 89 : 1148-, 2008

38 C. Fité, 33 : 581-, 1994

39 C. Buttersack, 10 : 143-, 1989

40 A. Chakrabarti, 20 : 1-, 1993

41 J. F. Izquierdo, 106 : 155-, 1993

42 R. S. Karinen, 188 : 247-, 1999

43 C. Fité, 44 : 2273-, 1998

44 D. Gubisch, "US Patent 6 015 928 A"

45 B. H. Gwynn, "US Patent 2 743 302 A"

46 C.L. Yaws, "Thermophysical Properties of Chemicals and Hydrocarbons" William Andrew 672-, 2008

47 R. Stewart, "The Proton: Applications to Organic Chemistry" Academic Press Inc. 1985

48 B. E. Poling, "The Properties of Gases and Liquids" McGraw-Hill 2001

49 R. C. Reid, "The Properties of Gases and Liquids" McGraw-Hill 1987

50 T. Matsuura, "Synthetic Membranes and Membrane Separation Processes" CRC Press Inc. 1993

51 S.M. Hosseini, "Preparation and characterization of PVC based heterogeneous ion exchange membrane coated with Ag nanoparticles by (thermal-plasma) treatment assisted surface modification" 한국공업화학회 19 (19): 854-862, 2013

52 R. González, "Performance of AmberlystTM 35 in the Synthesis of ETBE from Ethanol and C4 cuts" University of Barcelona 2011

53 O. Boonthamtirawuti, "Kinetics of liquid phase synthesis of tert-amyl ethyl ether from tert-amyl alcohol and ethanol over Amberlyst 16" 한국공업화학회 15 (15): 451-457, 2009

54 권택남, "Adsorption characteristics of sericite for nickel ions from industrial waste water" 한국공업화학회 19 (19): 68-72, 2013