<P><B>Abstract</B></P> <P>Clathrate hydrates, commonly called gas hydrates, are non-stoichiometric inclusion compounds with tunable gas storage and separation capabilities. Various efforts have been made to apply these h...
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https://www.riss.kr/link?id=A107741666
2017
-
SCOPUS,SCIE
학술저널
890-898(9쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<P><B>Abstract</B></P> <P>Clathrate hydrates, commonly called gas hydrates, are non-stoichiometric inclusion compounds with tunable gas storage and separation capabilities. Various efforts have been made to apply these h...
<P><B>Abstract</B></P> <P>Clathrate hydrates, commonly called gas hydrates, are non-stoichiometric inclusion compounds with tunable gas storage and separation capabilities. Various efforts have been made to apply these hydrates to energy and environmental fields including energy storage and greenhouse gas capture and separation technologies. Although the unary use of gaseous guest molecules such as methane, carbon dioxide, and nitrogen is generally expected to achieve maximal storage capacity by filling the guest in both small and large cages of each structure, introducing additional liquid guest molecules into the clathrate hydrates could be a more feasible option from an engineering perspective, since such liquid guest molecules often play a critical role in stabilization of the clathrate hydrate by shifting the thermodynamic phase equilibria to practically implementable milder pressure and temperature conditions. Here, we focus on the binary neopentyl alcohol clathrate hydrates with gaseous guest molecules, including carbon dioxide, methane, and nitrogen, to provide a better understanding of the complex nature of the host–guest interactions occurring in the clathrate hydrates. Thermodynamic <I>P</I> – <I>T</I> phase equilibria were measured, and spectroscopic analyses were performed employing HRPD, Raman, and NMR spectrometers. The results revealed that the NPA guest molecule forms sI or sII hydrate depending on the binary gaseous guest molecules. This paper also reports for the first time that the composition of CO<SUB>2</SUB> guest molecules may be ‘tuned’ within the cages of sI hydrate of NPA.</P> <P><B>Highlights</B></P> <P> <UL> <LI> The structures of binary NPA hydrates depend on the secondary gaseous guest. </LI> <LI> Binary (NPA+CO<SUB>2</SUB>) hydrate is investigated for application to CO<SUB>2</SUB> capture. </LI> <LI> The inclusion of NPA shifts the phase equilibrium boundary to a stable region. </LI> <LI> The CO<SUB>2</SUB> guest distribution is tuned by the NPA composition. </LI> </UL> </P>