Enhanced Arsenic(V) Removal from Aqueous Solution by a Novel Magnetic Biochar Derived from Dairy Cattle Manure

다국어 초록 (Multilingual Abstract)

Magnetic biochar produced from pyrolysis of dairy cattle manure was used to develop an effective sorbent for arsenic purification from aqueous solution. Biomass and magnetized biomass were pyrolyzed in a tube furnace with 10℃/min heating rate at 450℃ under nitrogen flow of 100 cm3/min for 2 h. Biochars were characterized by SEM-EDX, BET, XDR, FTIR, TGA, zeta potential analysis. The resultant biochar and magnetic biochar were opposed to 50-100- 500 ppm As(V) laden aqueous solution. Adsorption experiments were performed by using ASTM 4646-03 batch method.
The effects of concentration, pH, temperature and stirring rate on adsorption were evaluated. As(V) was successfully removed from aqueous solution by magnetic biochar due to its highly porous structure, high aromaticity and polarity.
The results suggest dairy cattle manure pyrolysis is a promising route for managing animal manure and producing a cost effective biosorbent for efficient immobilization of arsenic in aqueous solutions.

참고문헌 (Reference)

1 Duan, X., "Waste Walnut Shell Valorization to Iron Loaded Biochar and Its Application to Arsenic Removal" 3 : 29-36, 2017

2 Aredes, S, "The Removal of Arsenic from Water Using Natural Iron Oxide Minerals" 29-30 : 208-213, 2012

3 Inyang, M., "Synthesis, Characterization, and Dye Sorption Ability of Carbon Nanotube–Biochar Nanocomposites" 236 : 39-46, 2014

4 Thines, K. R., "Synthesis of Magnetic Biochar from Agricultural Waste Biomass to Enhancing Route for Waste Water and Polymer Application:A Review" 67 : 257-276, 2017

5 He, R., "Synthesis and Characterization of An Iron-Impregnated Biochar for Aqueous Arsenic Removal" 612 : 1177-1186, 2018

6 He, R., "Synthesis and Characterization of An Iron-Impregnated Biochar for Aqueous Arsenic Removal" 612 : 1177-1186, 2018

7 Akyürek, Z., "Sustainable Valorization of Animal Manure and Recycled Polyester: Co-pyrolysis Synergy" 11 (11): 2280-, 2019

8 Mukherjee, A., "Surface Chemistry Variations among A Series of Laboratory-Produced Biochars" 163 : 247-255, 2011

9 Indu Kaushal ; Sanjeev Maken ; Ashok Kumar Sharma, "SnO2 Mixed Banana Peel Derived Biochar Composite for Supercapacitor Application" 한국화학공학회 56 (56): 694-704, 2018

10 Regmi, P., "Removal of Copper and Cadmium from Aqueous Solution using Switchgrass Biochar Produced via Hydrothermal Carbonization Process" 109 : 61-69, 2012

11 Pehlivan, E., "Removal of As (V) from Aqueous Solutions by Iron Coated Rice Husk" 106 : 511-517, 2013

12 Zhang, M., "Removal of Arsenic, Methylene Blue, and Phosphate by Biochar/AlOOH Nanocomposite" 226 : 286-292, 2013

13 Lata, S., "Removal of Arsenic from Water Using Nano Adsorbents and Challenges: A Review" 166 : 387-406, 2016

14 Wang, S., "Removal of Arsenic by Magnetic Biochar Prepared from Pinewood and Natural Hematite" 175 : 391-395, 2015

15 Wang, S, "Regeneration of Magnetic Biochar Derived from Eucalyptus Leaf Residue for Lead(II) Removal" 186 : 360-364, 2015

16 Lata, S., "Regeneration of Adsorbents and Recovery of Heavy Metals: A Review" 12 : 1461-1478, 2015

17 Namduri, H., "Quantitative Analysis of Iron Oxides Using Fourier Transform Infrared Spectrophotometry" 50 : 2493-2497, 2008

18 Tang, J., "Preparation of a Novel Graphen Oxide/Fe-Mn Composite and Its Application for Aqueous Hg(II) Removal" 316 : 151-158, 2016

19 Chang, Q., "Preparation of Iron-Impregnated Granular Activated Carbon for Arsenic Removal from Drinking Water" 184 : 515-522, 2010

20 Marques Neto, J. D. O., "Preparation and Evaluation of Chitosan Beads Immobilized with Iron (III) for the Removal of As (III) and As (V) from Water" 24 (24): 121-132, 2013

21 Zhang, M., "Preparation and Characterization of a Novel Magnetic Biochar for Arsenic Removal" 130 : 457-462, 2013

22 Wang, S., "Physicochemical and Sorptive Properties of Biochars Derived from Woody and Herbaceous Biomass" 134 : 257-262, 2015

23 Leupin, O. X., "Oxidation and Removal of Arsenic (III) from Aerated Groundwater by Filtration through Sand and Zero-valent Iron" 39 (39): 1729-1740, 2005

24 Jia, Y., "Observation of Surface Precipitation of Arsenate on Ferrihydrite" 40 (40): 3248-3253, 2006

25 Kim, J., "Modeling a Novel Ion Exchange Process for Arsenic and Nitrate Removal" 38 (38): 2053-2062, 2004

26 Yijun Zhao ; Dongdong Feng ; Yu Zhang ; Wenbo Tang ; Shun Meng ; Yangzhou Guo ; Shaozeng Sun, "Migration of Alkali and Alkaline Earth Metallic Species and Structure Analysis of Sawdust Pyrolysis Biochar" 한국화학공학회 54 (54): 659-664, 2016

27 Li, H., "Mechanisms of Metal Sorption by Biochars" 178 : 466-478, 2017

28 Li, Y., "Manganese Oxide-Modified Biochars:Preparation, Characterization, and Sorption of Arsenate and Lead" 181 : 13-17, 2015

29 Banerjee, K., "Kinetic and Thermodynamic Aspects of Adsorption of Arsenic onto Granular Ferric Hydroxide (GFH)" 42 (42): 3371-3378, 2008

30 Jin, J. W., "Influence of Pyrolysis Temperature on Properties and Environmental Safety of Heavy Metals in Biochars Derived from Municipal Sewage Sludge" 320 : 417-426, 2016

31 Yang, Y., "Evaluation of Adsorption Potential of Bamboo Biochar for Metal-Complex Dye: Equilibrium, Kinetics and Artificial Neural Network Modeling" 11 : 1093-1100, 2014

32 Shi, J., "Enhanced Adsorption of As(III) on Chemically Modified Activated Carbon Fibers" 9 : 41-, 2019

33 Ahmad, M., "Effects of Pyrolysis Temperature on Soybean Stover and Peanut Shell-Derived Biochar Properties and TCE Adsorption in Water" 118 : 536-544, 2012

34 Baig, S. A., "Effect of Synthesis Methods on Magnetic Kans Grass Biochar for Enhanced As (III,V) Adsorption from Aqueous Solutions" 71 : 299-310, 2014

35 Smith, E., "Chemistry of Inorganic Arsenic in Soils" 31 : 557-563, 2002

36 Triolo, J. M, "Characteristics of Animal Slurry as a Key Biomass for Biogas Production in Denmark, Biomass Now-Sustainable Growth and Use" IntechOpen 2013

37 Agrafioti, E., "Ca and Fe Modified Biochars as Adsorbents of Arsenic and Chromium in Aqueous Solutions" 146 : 444-450, 2014

38 Kaygusuz, K., "Biomass for Efficiency and Sustainability Energy Utilization in Turkey" 5 : 332-341, 2016

39 Joseph, S. D, "Biochar for Carbon Sequestration, Reduction of Greenhouse Gas Emissions and Enhancement of Soil Fertility; A Review of the Materials Science" 2007

40 Velazquez-Pena, C, "As(V) Sorption by Different Natural Zeolite Frameworks Modified with Fe, Zr and FeZr" 273 : 133-141, 2019

41 Xue, Q., "Arsenite and Arsenate Binding to Ferrihydrite Organo-mineral Coprecipitate:Implications for Arsenic Mobility and Fate in Natural Environments" 224 : 103-110, 2019

42 Matschullat, J., "Arsenic in the Geosphere - A Review" 249 : 297-312, 2000

43 Viraraghavan, T., "Arsenic in Drinking Water Problems and Solutions" 40 : 69-76, 1999

44 Agrafioti, E., "Arsenic and Chromium Removal from Water using Biochars Derived from Rice Husk" 133 : 309-314, 2014

45 Lin, L, "Arsenic Removal in Aqueous Solution by a Novel Fe-Mn Modified Biochar Composite: Characterization and Mechanism" 144 : 514-521, 2017

46 Vitela-Rodriguez, A. V., "Arsenic Removal by Modified Activated Carbons with Iron Hydro(oxide) Nanoparticles" 114 : 225-231, 2013

47 Garelick, H., "Arsenic Pollution Sources" 197 : 17-60, 2008

48 Singh, R., "Arsenic Contamination, Consequences and Remediation Techniques:A Review" 112 : 247-270, 2015

49 Mandal, B. K., "Arsenic Around The World:A Review" 58 : 201-235, 2002

50 Qiu, W., "Arsenate Removal from Water by An Alumina-Modified Zeolite Recovered from Fly Ash" 148 (148): 721-726, 2007

51 Liu, Z., "Arsenate Removal from Water Using Fe3O4-Loaded Activated Carbon Prepared from Waste Biomass" 160 : 57-62, 2010

52 Gholami, M. M., "Application of Reverse Osmosis Technology for Arsenic Removal from Drinking Water" 200 : 725-727, 2006

53 Tan, X. F., "Application of Biochar for The Removal of Pollutants from Aqueous Solutions" 125 : 70-85, 2015

54 Pellera, F. M., "Adsorption of Cu(II)Ions from Aqueous Solutions on Biochars Prepared from Agricultural By-products" 96 : 35-42, 2012

55 Tong, X. J., "Adsorption of Cu(II) by Biochars Generated from Three Crop Straws" 172 : 828-834, 2011

56 Samsuri, A. W., "Adsorption of As(III) and As(V) by Fe Coated Biochars and Biochars Produced from Empty Fruit Bunch and Rice Husk" 1 : 981-988, 2013