Air-stable, hole-conductor-free high photocurrent perovskite solar cells with CH₃NH₃PbI₃–NiO nanoparticles composite

다국어 초록 (Multilingual Abstract)

<P><B>Abstract</B></P> <P>One of critical issues for practical applications of perovskite solar cells (PSCs) is how to enhance the photocurrent and air stability of the peovskite materials. Here, we report an air-stable, hole-conductor-free (HCF), high photocurrent PSC based on CH<SUB>3</SUB>NH<SUB>3</SUB>PbI<SUB>3</SUB>–NiO nanoparticles (MAPbI<SUB>3</SUB>–NiO NPs) composite. The composite solution contains highly dispersed NiO NPs in solution of CH<SUB>3</SUB>NH<SUB>3</SUB>I(MAI) and PbI<SUB>2</SUB>in dimethylformamide. By introducing the CH<SUB>3</SUB>NH<SUB>3</SUB>PbI<SUB>3</SUB>–NiO composite into the active layer, the HCF-PSCs with FTO/c-TiO<SUB>2</SUB>/mp-TiO<SUB>2</SUB>/MAPbI<SUB>3</SUB>–NiO/Au architecture have been fabricated under ambient conditions. This composite-based HCF-PSCs show a high photocurrent density (<I>J<SUB>sc</SUB> </I>) of 26.41mA/cm<SUP>2</SUP>, which is 97%of theoretical maximum (i.e., 27.2mA/cm<SUP>2</SUP>). Compared to the power conversion efficiency (PCE) of MAPbI<SUB>3</SUB>-based HCF-PSC (i.e., 5.43%), the MAPbI<SUB>3</SUB>–NiO NPs composite-based HCF-PSC showed a high PCE of 12.14%. This increase in PCE is mainly due to a remarkable increase in photocurrent density, suggesting that the MAPbI<SUB>3</SUB>–NiO composite enhances the charge carrier generation via improving photo-absorption and fast hole-conduction by NiO NPs. More interestingly, the composite-based HCF-PSCs without encapsulation showed remarkable air stability with retaining ~90% of its original PCE and ~94% of both <I>J<SUB>sc</SUB> </I> and FF for 60 days under ambient environment. XPS and IR spectra analysis revealed that Ni–O, Pb–O, C–O, Ni–N and N–NiO bonds attributed to strong chemical interaction between NiO and MAPbI<SUB>3</SUB> molecules enhance the air stability of MAPbI<SUB>3</SUB>–NiO composite based HCF-PSCs.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Air-stable, high photocurrent perovskite solar cells with CH<SUB>3</SUB>NH<SUB>3</SUB>PbI<SUB>3</SUB>-NiO composites. </LI> <LI> Increase in photocurrent due to enhanced light harvesting and fast hole-conduction. </LI> <LI> Remarkable air stability with retaining 90–94 % of original devices performance. </LI> <LI> Strong chemical interaction between NiO and CH<SUB>3</SUB>NH<SUB>3</SUB>PbI<SUB>3</SUB>, leading to air stability. </LI> </UL> </P> <P><B>Graphical abstract</B></P> <P>Conceptual illustration of air stable, hole-conductor-free high photocurrent perovskite solar cell based on CH<SUB>3</SUB>NH<SUB>3</SUB>PbI<SUB>3</SUB>–NiO nanoparticles composites.</P> <P>[DISPLAY OMISSION]</P>