Novel cobalt bis(dicarbollide) terminal alkynes with charge‐compensated group were synthesized by the cleavage reactions of oxonium derivatives of cobalt bis(dicarbollide) with N,N‐dimethylprop‐2‐yn‐1‐amine. The solid‐state molecular str...
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https://www.riss.kr/link?id=O112840322
2020년
-
1434-1948
1099-0682
SCI;SCIE;SCOPUS
학술저널
2658-2665 [※수록면이 p5 이하이면, Review, Columns, Editor's Note, Abstract 등일 경우가 있습니다.]
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
Novel cobalt bis(dicarbollide) terminal alkynes with charge‐compensated group were synthesized by the cleavage reactions of oxonium derivatives of cobalt bis(dicarbollide) with N,N‐dimethylprop‐2‐yn‐1‐amine. The solid‐state molecular str...
Novel cobalt bis(dicarbollide) terminal alkynes with charge‐compensated group were synthesized by the cleavage reactions of oxonium derivatives of cobalt bis(dicarbollide) with N,N‐dimethylprop‐2‐yn‐1‐amine. The solid‐state molecular structures of alkynes prepared from 1,4‐dioxane and tetrahydropyran derivatives of cobalt and iron bis(dicarbollide) were determined by single‐crystal X‐ray diffraction. A series of zwitterionic conjugates of cobalt/iron bis(dicarbollide) with cholesterol were prepared using the copper(I)‐catalyzed azide–alkyne cycloaddition reaction.
Novel cobalt bis(dicarbollide) terminal alkynes with charge‐compensated groups were synthesized. The solid‐state molecular structures of alkyne derivatives of iron and cobalt bis(1,2‐dicarbollide) were determined by single‐crystal X‐ray diffraction studies. The copper(I)‐catalyzed azide–alkyne cycloaddition reaction of these alkynes with azido‐cholesterol leads to new zwitterionic boron conjugates.
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