<P>We achieved for the first time the formation of a charge-transfer complex (CTC) between a novel hyperbranched polyimide (PI) and oligo-imide-functionalized graphene oxide (FGO), aiming for enhancing the dielectric properties of resulting PI-F...
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https://www.riss.kr/link?id=A107704986
2018
-
SCOPUS,SCIE
학술저널
6555-6565(11쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<P>We achieved for the first time the formation of a charge-transfer complex (CTC) between a novel hyperbranched polyimide (PI) and oligo-imide-functionalized graphene oxide (FGO), aiming for enhancing the dielectric properties of resulting PI-F...
<P>We achieved for the first time the formation of a charge-transfer complex (CTC) between a novel hyperbranched polyimide (PI) and oligo-imide-functionalized graphene oxide (FGO), aiming for enhancing the dielectric properties of resulting PI-FGO nanocomposites. This novel hyperbranched PI was derived from a new diamine <I>N</I><SUP>1</SUP>,<I>N</I><SUP>1</SUP>′-(4,4′-oxybis(4,1-phenylene))bis(<I>N</I><SUP>1</SUP>-(4-aminophenyl)benzene-1,4-diamine). The imide moieties were integrated on amine-FGO via a step-by-step condensation and thermal imidization approach. This FGO exhibited excellent compatibility with hyperbranched PI because of the formation of a CTC between two domains. In viscoelastic measurements, the dynamic storage modulus and glass-transition temperature of flexible PI-FGO nanocomposites increased linearly with increasing FGO contents. The synthesized nanocomposites revealed high mechanical properties with a tensile strength as high as 1.122 GPa. Thermogravimetric analysis demonstrates that these nanocomposite films exhibit high thermal stability up to 550 °C. Remarkably, the dielectric constant increases up to 42.47 at 8 wt % FGO loading with a dielectric loss as low as 0.0018 while maintaining the breakdown strength as high as 147.3 ± 4.5 MV/m.</P>
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