非水溶媒 Dimethylformamide中에서 구리(Ⅱ)-α-Benzoinoxime錯物의 電氣化學的還元 = Electrochemical Reduction of Copper(Ⅱ)-α-Benzoinoxime Complex in Dimethylformamide as Non-Aqueous Solvent

다국어 초록 (Multilingual Abstract)

The electrochemical reduction of copper(Ⅱ)-α-benzoinoxime complex in N,N-dimethylformamide as a non-aqueous solvent has been studied by polarography and chronopotentiometry.
The copper(Ⅱ)-α-benzoinoxime complex was reduced to Cu(Hg) via two step involving two electrons as a whole. And the copper(Ⅱ) complex showed irreversible polarograms at a dropping mercury electrode and chronopotentiograms at a platinum electrode, which were all diffusion controlled. The half-wave potentials for the polarographic reduction of the copper(Ⅱ) complex were +0.15 and -0.22 volts versus a saturated calomel electrode.
The quater potentials for the chronopotentiometric reduction of the copper(Ⅱ) complex were -0.66 and -1.73 volts versus the saturated calomel electrode.