A series of picolyl‐functionalised, fluorescent 1,8‐naphthalimide ligands (L) have been synthesised and coordinated to ReI to form luminescent cationic complexes of the general form fac‐[Re(phen)(CO)3(L)]BF4. The complexes were characterised by ...
http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
https://www.riss.kr/link?id=O120787786
2017년
-
1434-1948
1099-0682
SCI;SCIE;SCOPUS
학술저널
5279-5287 [※수록면이 p5 이하이면, Review, Columns, Editor's Note, Abstract 등일 경우가 있습니다.]
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
A series of picolyl‐functionalised, fluorescent 1,8‐naphthalimide ligands (L) have been synthesised and coordinated to ReI to form luminescent cationic complexes of the general form fac‐[Re(phen)(CO)3(L)]BF4. The complexes were characterised by ...
A series of picolyl‐functionalised, fluorescent 1,8‐naphthalimide ligands (L) have been synthesised and coordinated to ReI to form luminescent cationic complexes of the general form fac‐[Re(phen)(CO)3(L)]BF4. The complexes were characterised by using a range of spectroscopic and analytical techniques. One example of a complex was also characterised in the solid‐state by using single‐crystal X‐ray diffraction, revealing a distorted octahedral coordination sphere at ReI and Re–C/Re–N bond lengths within the expected ranges. All ligands were shown to be fluorescent, with the 4‐amino derivatives showing intramolecular charge transfer in the visible region (511–534 nm). The complexes generally showed a mixture of ligand‐centred and/or 3MLCT emission depending upon the nature of the coordinated 1,8‐naphthalimide ligand. For selected complexes, confocal fluorescence microscopy was undertaken by using fission yeast cells (Schizosaccharomyces pombe) and showed that the structure of the 1,8‐naphthalimide ligand influences the uptake and localisation of the rhenium complex.
1,8‐Naphthalimide‐derived, picolyl‐based ligands have been coordinated to ReI to form luminescent complexes. The complexes were characterised by using an array of spectroscopic methods, and one example provided an X‐ray crystal structure. Selected complexes were explored as fluorescence cell imaging agents by using fission yeast cells.
Efficient Phosphorescence from Naphthalenebenzimidizole‐Coordinated Iridium(III) Chromophores