Design, Synthesis, and Crystallization‐Induced Emission of Boron Difluorides β‐Ketoiminates

다국어 초록 (Multilingual Abstract)

A series of new nitrogen‐containing analogues of boron difluoride benzoylacetonates with hydrogen and methyl substituents at the nitrogen atom have been synthesized. A comparative study of boron difluoride β‐ketoiminates and their oxygen‐containing analogues by means of luminescence and IR spectroscopic methods as well as quantum chemistry simulations was also performed.
Making light work: A series of new nitrogen‐containing analogues of boron difluoride benzoylacetonates with hydrogen and methyl substituents at the nitrogen atom have been synthesized (see figure). It was established that the luminescence of crystals of boron difluoride β‐ketoiminates depends on the nature of the substituent at the nitrogen atom.