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      첨가제를 이용한 보일러 열교환기의 고온부식 방지기술 현황 = A Technical Review on the Protective Measures of High Temperature Corrosion of Boiler Heat Exchangers with Additives

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      https://www.riss.kr/link?id=A105116460

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      국문 초록 (Abstract)

      기후변화 대응을 위한 청정 화력발전 기술의 일환으로 폐기물과 바이오매스를 중심으로 한 신재생연료의 이용이 크게 증가함에 따라 특히 고온·고압 스팀 생산이 필요한 발전용 보일러 열교환기의 고온부식(High temperature corrosion) 문제가 심각한 현안으로 대두되고 있다. 이러한 문제점은 저급연료에 포함된 염화알칼리 성분이 보일러 내 열교환기 중 표면온도가 가장 높은 과열기(Superheater) 또는 재열기(Reheater)에 점착된 후 염소에 의해 부식이 가속화되어 일어난다. 이를 해결하기위해 설계 변경, 재료 개선, 연료 전처리 등의 고온부식 회피 방법과 함께 첨가제를 이용한 고온부식 방지 기술이 활용되고있다. 본 연구에서는 보일러에서 고온부식 방지를 위한 다양한 접근 중 특히 첨가제를 이용한 연구개발 현황을 소개한다.
      번역하기

      기후변화 대응을 위한 청정 화력발전 기술의 일환으로 폐기물과 바이오매스를 중심으로 한 신재생연료의 이용이 크게 증가함에 따라 특히 고온·고압 스팀 생산이 필요한 발전용 보일러 열...

      기후변화 대응을 위한 청정 화력발전 기술의 일환으로 폐기물과 바이오매스를 중심으로 한 신재생연료의 이용이 크게 증가함에 따라 특히 고온·고압 스팀 생산이 필요한 발전용 보일러 열교환기의 고온부식(High temperature corrosion) 문제가 심각한 현안으로 대두되고 있다. 이러한 문제점은 저급연료에 포함된 염화알칼리 성분이 보일러 내 열교환기 중 표면온도가 가장 높은 과열기(Superheater) 또는 재열기(Reheater)에 점착된 후 염소에 의해 부식이 가속화되어 일어난다. 이를 해결하기위해 설계 변경, 재료 개선, 연료 전처리 등의 고온부식 회피 방법과 함께 첨가제를 이용한 고온부식 방지 기술이 활용되고있다. 본 연구에서는 보일러에서 고온부식 방지를 위한 다양한 접근 중 특히 첨가제를 이용한 연구개발 현황을 소개한다.

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      다국어 초록 (Multilingual Abstract)

      As the use of waste and biomass increases in a power generation boiler, high temperature corrosion (HTC) problems of boiler heat exchangers are becoming very important. Chlorine of the low-rank fuels is mainly responsible for the HTC issues, which typically occur in the surface of high temperature heat exchanger like a superheater or reheater. In order to mitigate the problem, various approaches have been proposed in terms of design modification, material improvement, fuel pre-treatment and additive utilization. In this study, the current state of research and development focused on the additive method was investigated.
      번역하기

      As the use of waste and biomass increases in a power generation boiler, high temperature corrosion (HTC) problems of boiler heat exchangers are becoming very important. Chlorine of the low-rank fuels is mainly responsible for the HTC issues, which typ...

      As the use of waste and biomass increases in a power generation boiler, high temperature corrosion (HTC) problems of boiler heat exchangers are becoming very important. Chlorine of the low-rank fuels is mainly responsible for the HTC issues, which typically occur in the surface of high temperature heat exchanger like a superheater or reheater. In order to mitigate the problem, various approaches have been proposed in terms of design modification, material improvement, fuel pre-treatment and additive utilization. In this study, the current state of research and development focused on the additive method was investigated.

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      참고문헌 (Reference)

      1 이동복, "바이오매스 발전시 염소가스에 의한 고온부식" 한국표면공학회 49 (49): 14-19, 2016

      2 Zhang, S, "Transformation of Chlorine in NaCl-loaded Victorian Brown Coal during the Gasification in Steam" 40 (40): 1409-1414, 2012

      3 Uberoi, M, "The Kinetics and Mechanism of Alkali Removal from Flue Gases by Solid Sorbents" 16 (16): 205-211, 1990

      4 Pettersson, J, "The Influence of Sulphur Additions on the Corrosive the Environment in a Waste-Fired CFB Boiler" 522-, 2006

      5 Kassman, H, "The Importance of SO2 and SO3 for Sulphation of Gaseous KCl - An Experimental Investigation in a Biomass Fired CFB Boiler" 157 : 1649-1657, 2010

      6 Fernández Llorente, M. J, "The Effect of the Addition of Chemical Materials on the Sintering of Biomass Ash" 87 (87): 2651-2658, 2008

      7 Kassman, H, "The Effect of Oxygen and Volatile Combustible on the Sulphation of Gaseous KCl" 160 : 2231-2241, 2013

      8 Viklund, P, "Superheater Corrosion in Biomass and Waste Fired Boilers" KTH 2013

      9 Andersson, S, "Sulfur Recirculation for Increased Electricity Production in Waste-to-Energy Plants" 34 : 67-78, 2014

      10 Broström, M, "Sulfation of Corrosive Alkali Chlorides by Ammonium Sulfate in a Biomass Fired CFB Boiler" 88 : 1171-1177, 2007

      1 이동복, "바이오매스 발전시 염소가스에 의한 고온부식" 한국표면공학회 49 (49): 14-19, 2016

      2 Zhang, S, "Transformation of Chlorine in NaCl-loaded Victorian Brown Coal during the Gasification in Steam" 40 (40): 1409-1414, 2012

      3 Uberoi, M, "The Kinetics and Mechanism of Alkali Removal from Flue Gases by Solid Sorbents" 16 (16): 205-211, 1990

      4 Pettersson, J, "The Influence of Sulphur Additions on the Corrosive the Environment in a Waste-Fired CFB Boiler" 522-, 2006

      5 Kassman, H, "The Importance of SO2 and SO3 for Sulphation of Gaseous KCl - An Experimental Investigation in a Biomass Fired CFB Boiler" 157 : 1649-1657, 2010

      6 Fernández Llorente, M. J, "The Effect of the Addition of Chemical Materials on the Sintering of Biomass Ash" 87 (87): 2651-2658, 2008

      7 Kassman, H, "The Effect of Oxygen and Volatile Combustible on the Sulphation of Gaseous KCl" 160 : 2231-2241, 2013

      8 Viklund, P, "Superheater Corrosion in Biomass and Waste Fired Boilers" KTH 2013

      9 Andersson, S, "Sulfur Recirculation for Increased Electricity Production in Waste-to-Energy Plants" 34 : 67-78, 2014

      10 Broström, M, "Sulfation of Corrosive Alkali Chlorides by Ammonium Sulfate in a Biomass Fired CFB Boiler" 88 : 1171-1177, 2007

      11 Gilbe, C, "Slagging Characteristics during Residential Combustion of Biomass Pellets" 22 (22): 3536-3543, 2008

      12 Lindström, E, "Slagging Characteristics during Combustion of Cereal Grains Rich in Phosphorus" 21 (21): 710-717, 2007

      13 Wang, L, "Sintering Characteristics of Sewage Sludge Ashes at Elevated Temperatures" 96 : 88-97, 2012

      14 Elled, A. L, "Sewage Sludge as a Deposit Inhibitor when Co-Fired with High Potassium Fuels" 34 : 1546-1554, 2010

      15 Kyi, S, "Screening of Potential Mineral Additives for use as Fouling Preventatives in Victorian Brown Coal Combustion" 78 : 845-855, 1999

      16 Rahim, M. U, "Release of Chlorine from the Slow Pysolysis of NaCl-loaded Cellulose at Low Temperatures" 35 : 2891-2896, 2015

      17 Bläsing, M, "Release of Alkali Metal, Sulphur and Chlorine Species during High-Temperature Gasification and Co-Gasification of Hard Coal, Refinery Residue, and Petroleum Coke" 126 : 62-68, 2014

      18 Hjörnhede, A, "Reduction of Furnace Wall Corrosion by the use of Fuel Additives Tests in Fluidised Bed Test Rig with Waste and Demolition Wood" 2014

      19 Henderson, P, "Reducing Superheater Corrosion in Wood-Fired Boilers" 57 (57): 128-134, 2006

      20 Leckner, B, "Properties and Refinements of Biomass Fuels" 2011

      21 Forsberg, C, "Principle, Calibration, and Application of the in Situ Alkali Chloride Monitor" 80 : 2009

      22 Aho, M, "Preventing Chlorine Deposition on Heat Transfer Surfaces with Aluminium - Silicon Rich Biomass Residue and Additive" 83 : 1299-1305, 2004

      23 Glazer, M, "Practical Experiences with Mitigating HT Corrosion by the ChlorOut Concept in Full Scale Boilers" 2014

      24 Wu, H, "Modeling of Sulfation of Potassium Chloride by Ferric Sulfate Addition during Gratefiring of Biomass" International Flame Research Foundation 2013

      25 Paneru, M, "Mineral Additives to Mitigate Deposition and Corrosion Problems during Pulverized Biomass Combustion" 2016

      26 Glaborg, P, "Mechanism and Modeling of the Formation of Gaseous Alkali Sulfates" 141 (141): 22-39, 2005

      27 Dean, J. A, "Lange’s Handbook of Chemistry" McGraw-Hill 1999

      28 Wang, G, "K-capture by al-si based Additives in an Entrained Flow Reactor" 2016

      29 Steenari, B. M, "Investigation of Ash Sintering during Combustion of Agricultural Residues and the Effect of Additives" 23 (23): 5655-5662, 2009

      30 Jiménez, S, "Influence of Operating Conditions and the Role of Sulfur in the Formation of Aerosols from Biomass Combustion" 140 : 346-358, 2005

      31 Steenari, B. M, "High-temperature Reactions of Straw Ash and the Anti-Sintering Additives Kaolin and Dolomite" 14 (14): 67-76, 1998

      32 Kawahara, Y, "High temperature Corrosion Mechanisms and Effect of Alloying Elements for Materials used in Waste Incineration Environment" 44 (44): 223-245, 2002

      33 Thy, P, "High Temperature Elemental Losses and Mineralogical Changes in Common Biomass Ashes" 85 : 783-795, 2006

      34 Jiménez, S, "Formation of Alkali Sulphate Aerosols in Biomass Combustion" 86 : 486-493, 2007

      35 Bale, C. W, "FactSage Thermochemical Software and Databases - Recent Developments" 33 (33): 295-311, 2009

      36 Yrjas, P, "FBC Challenges : Current Research at ÅAUniversity" 2015

      37 Vainio, E, "Experimental Evaluation and Field Application of a Salt Method for SO3 Measurement in Flue Gases" 27 : 2767-2775, 2013

      38 Thy, P, "Experimental Determination of High-Temperature Elemental Losses from Biomass Slag" 79 (79): 693-700, 2000

      39 Reese, E, "Einfluß von Natriumchlorid auf Die Oxidation von Hochlegierten Chrom- und Chrom-Nickel-Stählen" 44 (44): 41-47, 1993

      40 Reese, E, "Einfluß von Chloriden auf Die Oxidation des 2¼ Cr-1 Mo-Stahls" 43 (43): 547-557, 1992

      41 Wang, L, "Effects of Sewage Sludge and Marble Sludge Addition on Slag Characteristics during Wood Waste Pellets Combustion" 25 : 5775-5785, 2011

      42 Aho, M, "Effective New Chemicals to Prevent Corrosion due to Chlorine in Power Plant Superheaters" 87 : 647-654, 2008

      43 Wu, H, "Dust-Firing of Straw and Additives: Ash Chemistry and Deposition Behavior" 25 : 2862-2873, 2011

      44 Åmand, L. E, "Deposits on Heat Transfer Tubes during Co-Combustion of Biofuels and Sewage Sludge" 85 (85): 1313-1322, 2006

      45 Tobiasen, L, "Deposit Characteristic after Injection of Additives to a Danish Straw-Fired Suspension Boiler" 88 (88): 1108-1117, 2007

      46 Johansson, L-G, "Critical High Temperature Corrosion Issues in Biomass-Fired Powerplants" 2014

      47 Sharp, S, "Could Biomass Boilers be Operated at Higher Steam Efficiencies (Higher Temps.)" 2014

      48 Tillman, D. A, "Chlorine in Solid Fuels Fired in Pulverized Fuel Boilers - Sources, Forms, Reactions, and Consequences: a Literature Review" 23 : 3379-3391, 2009

      49 Pettersson, A, "Chemical Fractionation for the Characterization of Fly Ashes from Co-Combustion of Biofuels using Different Methods for Alkali Reduction" 88 : 1758-1772, 2009

      50 Grimm, A, "Bed Agglomeration Characteristics in Fluidized Quartz Bed Combustion of Phosphorus-Rich Biomass Fuels" 25 (25): 937-947, 2011

      51 Hindiyart, L, "An Exploratory Study of Alkali Sulfate Aerosol Formation during Biomass Combustion" 87 (87): 1591-1600, 2008

      52 Wang, L, "A critical Review on Additives to Reduce Ash Related Operation Problems in Biomass Combustion Applications" 20 : 20-29, 2012

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      연월일 이력구분 이력상세 등재구분
      2027 평가예정 재인증평가 신청대상 (재인증)
      2021-01-01 평가 등재학술지 유지 (재인증) KCI등재
      2018-11-01 학술지명변경 한글명 : 청정기술 -> Clean Technology
      외국어명 : CLEAN TECHNOLOGY -> Clean Technology
      KCI등재
      2018-01-01 평가 등재학술지 유지 (등재유지) KCI등재
      2015-01-01 평가 등재학술지 유지 (등재유지) KCI등재
      2011-01-01 평가 등재학술지 유지 (등재유지) KCI등재
      2008-01-01 평가 등재학술지 선정 (등재후보2차) KCI등재
      2007-07-04 학술지명변경 한글명 : 한국청정기술학회지 -> 청정기술 KCI등재후보
      2007-01-01 평가 등재후보 1차 PASS (등재후보1차) KCI등재후보
      2005-01-01 평가 등재후보학술지 선정 (신규평가) KCI등재후보
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      기준연도 WOS-KCI 통합IF(2년) KCIF(2년) KCIF(3년)
      2016 0.26 0.26 0.25
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