The first photoinduced carbon(sp2)–heteroatom bond forming reaction by a rare‐earth‐metal photoreductant, a Miyaura borylation, has been achieved. This simple, scalable, and novel borylation method that makes use of the hexachlorocerate(III) ani...
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https://www.riss.kr/link?id=O120453408
2018년
-
1433-7851
1521-3773
SCI;SCIE;SCOPUS
학술저널
10999-11003 [※수록면이 p5 이하이면, Review, Columns, Editor's Note, Abstract 등일 경우가 있습니다.]
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
The first photoinduced carbon(sp2)–heteroatom bond forming reaction by a rare‐earth‐metal photoreductant, a Miyaura borylation, has been achieved. This simple, scalable, and novel borylation method that makes use of the hexachlorocerate(III) ani...
The first photoinduced carbon(sp2)–heteroatom bond forming reaction by a rare‐earth‐metal photoreductant, a Miyaura borylation, has been achieved. This simple, scalable, and novel borylation method that makes use of the hexachlorocerate(III) anion ([CeIIICl6]3−, derived from CeCl3) has a broad substrate scope and functional‐group tolerance and can be conducted at room temperature. Combined with Suzuki–Miyaura cross‐coupling, the method is applicable to the synthesis of various biaryl products, including through the use of aryl chloride substrates.
Salt of the earth: The first photoinduced Miyaura borylation mediated by a rare‐earth‐metal photoreductant, namely the hexachlorocerate(III) anion ([CeIIICl6]3−), is reported. This operationally simple, scalable, and practical borylation method has a broad substrate scope and functional‐group tolerance.
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