<P>New versatile host materials with good solubility in common organic solvents are greatly desired to promote solution-processable thermally activated delayed fluorescence organic light-emitting diodes. This paper describes the design and synth...
http://chineseinput.net/에서 pinyin(병음)방식으로 중국어를 변환할 수 있습니다.
변환된 중국어를 복사하여 사용하시면 됩니다.
https://www.riss.kr/link?id=A107447030
2018
-
SCIE
학술저널
10000-10009(10쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<P>New versatile host materials with good solubility in common organic solvents are greatly desired to promote solution-processable thermally activated delayed fluorescence organic light-emitting diodes. This paper describes the design and synth...
<P>New versatile host materials with good solubility in common organic solvents are greatly desired to promote solution-processable thermally activated delayed fluorescence organic light-emitting diodes. This paper describes the design and synthesis of two new host materials, namely 3′-(9<I>H</I>-carbazol-9-yl)-[1,1′-biphenyl]-3,5-diylbis(diphenylphosphine oxide) (CDPO) and 3′,5′-di-(9<I>H</I>-carbazol-9-yl)-[1,1′-biphenyl]-3,5-diylbis (diphenylphosphine oxide) (mCPDPO), featuring hole-transporting carbazole and electron-transporting diphenylphosphine oxide (DPO) entities. The donor strength was varied to a constant n-type DPO core to tune the functional properties. The detailed studies proved that the resulting two new materials exhibit excellent solubility in common organic solvents, high triplet energy (@@>@@2.80 eV), high glass transition temperature (up to 133 °C), and good bipolar electronic nature. Consequently, both compounds were used as hosts in solution-processable blue and green thermally activated delayed fluorescence (TADF) OLEDs. In particular, the devices using mCPDPO as a host in the emissive layer showed outstanding performance with a maximum current efficiency, power efficiency, and external quantum efficiency of 35.3 cd A<SUP>−1</SUP>, 17.0 lm W<SUP>−1</SUP> and 15.4% in the blue-emitting diode, and 61.5 cd A<SUP>−1</SUP>, 29.7 lm W<SUP>−1</SUP> and 18.8% in the green-emitting diode, respectively. These results corroborated the potential of carbazole-phosphine oxide derivatives as host materials in solution-processable blue and green TADF OLEDs.</P>