Excess molar enthalpy (H<SUB>m</SUB><SUP>E</SUP>) have been measured at 303.15K for 1-propanol+benzene or toluene or o- or m- or p-xylene mixtures using flow micro calorimeter. The H<SUB>m</SUB><SUP>E</SUP&...
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https://www.riss.kr/link?id=A107479292
2015
-
학술저널
299-306(8쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
Excess molar enthalpy (H<SUB>m</SUB><SUP>E</SUP>) have been measured at 303.15K for 1-propanol+benzene or toluene or o- or m- or p-xylene mixtures using flow micro calorimeter. The H<SUB>m</SUB><SUP>E</SUP&...
Excess molar enthalpy (H<SUB>m</SUB><SUP>E</SUP>) have been measured at 303.15K for 1-propanol+benzene or toluene or o- or m- or p-xylene mixtures using flow micro calorimeter. The H<SUB>m</SUB><SUP>E</SUP>versusx<SUB>1</SUB> plots are skewed toward y-axis showing maxima at x<SUB>1</SUB>~0.3. At (x<SUB>1</SUB>=0.5)H<SUB>m</SUB><SUP>E</SUP> vary in the order: toluene<benzene<m-xylene<p-xylene~o-xylene. The excess volume data have also been interpreted in terms of Graph-theoretical approach and Prigogine-Flory-Patterson theory. It has been observed that while PFP theory fails to predict the H<SUB>m</SUB><SUP>E</SUP> values for these systems in the composition range x<SUB>1</SUB><0.5, agreement with experimental values is reasonably good thereafter. The H<SUB>m</SUB><SUP>E</SUP> values calculated by Graph theory compared well with the corresponding experimental values.
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