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      Ni-YSZ Core-shell에서 Shell의 두께에 따른 SOFC의 출력특성 = Performance of SOFC According to Thickness of Shell with Ni-YSZ Core-shell

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      https://www.riss.kr/link?id=A105228100

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      다국어 초록 (Multilingual Abstract)

      SOFC anode fabricated core-shell using machano-fusion method using core with submicron size Ni, nano size YSZ for shell. Using prepared core-shell, depending on the thickness of the shell, we studied how the characteristics of sintering and SOFC cell change by sintering the anode. The Ni-YSZ core-shell has a Ni core of 0.5 to 1.2 μm over 2 to 7 YSZ of 15 to 20 nm is, and as the high speed mixing time increases, the YSZ number increases and the shell thickness becomes uniform increased. When the fuel electrode is manufactured with core-shell, it has superior sintering property, has grain of uniform size compared with the one synthesized by general mixing, the falling path is short, the conductors (electrons and ions) connection is excellent, the electrical conductivity has become excellent. The thicker the shell, the lower the electrical conductivity. When the thickness of shell ranged from 46 to 139 nm and 61 to 81 nm, the performance was the highest and the ASR was the smallest.
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      SOFC anode fabricated core-shell using machano-fusion method using core with submicron size Ni, nano size YSZ for shell. Using prepared core-shell, depending on the thickness of the shell, we studied how the characteristics of sintering and SOFC cell ...

      SOFC anode fabricated core-shell using machano-fusion method using core with submicron size Ni, nano size YSZ for shell. Using prepared core-shell, depending on the thickness of the shell, we studied how the characteristics of sintering and SOFC cell change by sintering the anode. The Ni-YSZ core-shell has a Ni core of 0.5 to 1.2 μm over 2 to 7 YSZ of 15 to 20 nm is, and as the high speed mixing time increases, the YSZ number increases and the shell thickness becomes uniform increased. When the fuel electrode is manufactured with core-shell, it has superior sintering property, has grain of uniform size compared with the one synthesized by general mixing, the falling path is short, the conductors (electrons and ions) connection is excellent, the electrical conductivity has become excellent. The thicker the shell, the lower the electrical conductivity. When the thickness of shell ranged from 46 to 139 nm and 61 to 81 nm, the performance was the highest and the ASR was the smallest.

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      참고문헌 (Reference)

      1 Y. Okawa, "Thermal stability of nanometer-sized NiO and Sm-doped ceria powders" 17 (17): 2266-2274, 2002

      2 S. T. Aruna, "Synthesis and properties of Ni-YSZ cermet: anode material for solid oxide fuel cells" 111 (111): 45-51, 1998

      3 Min-Jin Lee, "Synthesis and Characterization of Spherical Nano Ni (1-x) -M (x=0~0.15) (M=Co, Fe) Alloy Powder for SOFC Anode" Korean Ceramic Society 51 (51): 367-373, 2014

      4 S. P. Jing, "Sintering Behavior of Ni/Y2O3-ZrO2 Cermet Electrodes of Solid Oxide Fuel Cells" 38 (38): 3775-3782, 2003

      5 C. H. Kuo, "Rigidity and Conductivity Percolation Thresholds in Particulate Composites" 43 (43): 397-403, 1995

      6 D. Simwonis, "Properties of Ni/YSZ porous cermets for SOFC anode substrates prepared by tape casting and coat-mixⓇ process" 92 : 107-111, 1999

      7 P. Duran, "Processing and characterisation of a fine nickel oxide/zirconia/composite prepared by polymeric" 23 (23): 2125-2133, 2003

      8 G. Q. Shao, "Preparation of nanocomposite Ni/YSZ cermet powder by EDTA complexes. gel conversion process" 57 (57): 3287-3290, 2003

      9 M. Marinsek, "Preparation of Ni-YSZ Composite Materials for Solid Oxide Fuel Cell Anodes by the Gel-percipitation" 86 (86): 383-389, 2000

      10 S. D. Kim, "Performance and Durability of Ni-coated YSZ Anodes for Intermediate Temperature Solid Oxide Fuel Cells" 177 (177): 931-938, 2006

      1 Y. Okawa, "Thermal stability of nanometer-sized NiO and Sm-doped ceria powders" 17 (17): 2266-2274, 2002

      2 S. T. Aruna, "Synthesis and properties of Ni-YSZ cermet: anode material for solid oxide fuel cells" 111 (111): 45-51, 1998

      3 Min-Jin Lee, "Synthesis and Characterization of Spherical Nano Ni (1-x) -M (x=0~0.15) (M=Co, Fe) Alloy Powder for SOFC Anode" Korean Ceramic Society 51 (51): 367-373, 2014

      4 S. P. Jing, "Sintering Behavior of Ni/Y2O3-ZrO2 Cermet Electrodes of Solid Oxide Fuel Cells" 38 (38): 3775-3782, 2003

      5 C. H. Kuo, "Rigidity and Conductivity Percolation Thresholds in Particulate Composites" 43 (43): 397-403, 1995

      6 D. Simwonis, "Properties of Ni/YSZ porous cermets for SOFC anode substrates prepared by tape casting and coat-mixⓇ process" 92 : 107-111, 1999

      7 P. Duran, "Processing and characterisation of a fine nickel oxide/zirconia/composite prepared by polymeric" 23 (23): 2125-2133, 2003

      8 G. Q. Shao, "Preparation of nanocomposite Ni/YSZ cermet powder by EDTA complexes. gel conversion process" 57 (57): 3287-3290, 2003

      9 M. Marinsek, "Preparation of Ni-YSZ Composite Materials for Solid Oxide Fuel Cell Anodes by the Gel-percipitation" 86 (86): 383-389, 2000

      10 S. D. Kim, "Performance and Durability of Ni-coated YSZ Anodes for Intermediate Temperature Solid Oxide Fuel Cells" 177 (177): 931-938, 2006

      11 Y. T. An, "New fabrication technique for a Ni–YSZ composite anode from a core–shell structured particle" 207 : 64-68, 2012

      12 T. Fukui, "Long‐Term Stability of Ni‐YSZ Anode with a New Microstructure Prepared from Composite Powder" 1 : 120-122, 1998

      13 R. M. C. Clemmer, "Influence of Porous Composite Microstructure on the Processing and Properties of Solid Oxide Fuel Cell Anodes" 166 (166): 251-259, 2004

      14 S. P. Yoon, "Improvement of Anode Performance by Surface Modification for Solid Oxide Fuel Cell Running on Hydrocarbon Fuel" 136 (136): 30-36, 2004

      15 강영진, "Electrical Conductivity of Ni-YSZ Anode for SOFCs According to the Ni Powder Size Variations in Core-shell Structure" 대한금속·재료학회 53 (53): 287-293, 2015

      16 A. Atkinson, "Advanced Anodes for High-temperature Fuel Cells" 3 : 17-27, 2004

      17 S. P. Jiang, "A Review of Anode Materials Development in Solid Oxide Fuel Cells" 39 (39): 4405-4439, 2004

      18 Z. Zhu, "A Reivew on the Status of Anode Materials for Solid Oxide Fuel Cells" 362 (362): 1229-1239, 2003

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