We report the first spectroscopic observation of the 2-chloro-m-xylyl radical in the gas phase. The vibronically excited but jet-cooled 2-chloro-m-xylyl radical was generated from the corona discharge of the precursor, 2-chloro-m-xylene seede...
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https://www.riss.kr/link?id=A107625867
2012
-
SCOPUS,SCIE
학술저널
44-48(5쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
We report the first spectroscopic observation of the 2-chloro-m-xylyl radical in the gas phase. The vibronically excited but jet-cooled 2-chloro-m-xylyl radical was generated from the corona discharge of the precursor, 2-chloro-m-xylene seede...
We report the first spectroscopic observation of the 2-chloro-m-xylyl radical in the gas phase. The vibronically excited but jet-cooled 2-chloro-m-xylyl radical was generated from the corona discharge of the precursor, 2-chloro-m-xylene seeded in a large amount of inert carrier gas He. The well-resolved vibronic emission spectrum of the 2-chloro-m-xylyl radical was recorded using a long path monochromator in the visible region. The spectrum was analyzed to obtain accurate measurements of the energy of the D<SUB>1</SUB>->D<SUB>0</SUB> electronic transition and the vibrational modes frequencies in the ground electronic state by comparison with those from an ab initio calculation and the known vibrational data of the precursor.