Syngas conversion by Fischer–Tropsch synthesis (FTS) is characterized by a wide distribution of hydrocarbon products ranging from one to a few carbon atoms. Reported here is that the product selectivity is effectively steered toward ethylene by empl...
Syngas conversion by Fischer–Tropsch synthesis (FTS) is characterized by a wide distribution of hydrocarbon products ranging from one to a few carbon atoms. Reported here is that the product selectivity is effectively steered toward ethylene by employing the oxide‐zeolite (OX‐ZEO) catalyst concept with ZnCrOx‐mordenite (MOR). The selectivity of ethylene alone reaches as high as 73 % among other hydrocarbons at a 26 % CO conversion. This selectivity is significantly higher than those obtained in any other direct syngas conversion or the multistep process methanol‐to‐olefin conversion. This highly selective pathway is realized over the catalytic sites within the 8‐membered ring (8MR) side pockets of MOR via a ketene intermediate rather than methanol in the 8MR or 12MR channels. This study provides substantive evidence for a new type of syngas chemistry with ketene as the key reaction intermediate and enables extraordinary ethylene selectivity within the OX‐ZEO catalyst framework.
Die Achterring‐Seitentaschen von Mordenit überführen Keten‐Zwischenstufen, die während der Syngas‐Umwandlung auf ZnCrOx gebildet werden, effizient in Ethylen; die Selektivität für Ethylen erreicht 73 % bei einem CO‐Umsatz von 26 %. Die Zwölferringe von MOR setzen dagegen bevorzugt Methanol als Zwischenstufe um und liefern eine deutlich abweichende Produktverteilung mit Schwerpunkt auf längerkettigen Kohlenwasserstoffen. MOR=Mordenit‐Zeolith.