Effect of H₂ spillover rate as functon of reduction temperature on reaction kinetics was
evaluated. Reaction kinetics including yield, conversion, activation energy and selectivity of 1-butene
isomerization over Pt/MoOx/SiO₂ were measured as react...
Effect of H₂ spillover rate as functon of reduction temperature on reaction kinetics was
evaluated. Reaction kinetics including yield, conversion, activation energy and selectivity of 1-butene
isomerization over Pt/MoOx/SiO₂ were measured as reaction temperature was increased. While
conversion of 1-butene was decreased, yield of isobutene was increased. Two kinds of reaction
mechanism would be proposed from the change of selectivity as function of reduction temperature.