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      전이금속으로 개질된 Red Mud 촉매상에서 휘발성유기화합물 제거 = Removal of Volatile Organic Compounds on Red Mud Catalyst Modified with Transition Metals

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      https://www.riss.kr/link?id=A106847174

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      다국어 초록 (Multilingual Abstract)

      Red mud(RM), a byproduct of alumina production, was incorporated with a transition metal, which was used as a catalyst for oxidation of volatile organic compounds (VOCs). RM was treated with hydrochloric acid and ammonia and then calcined at 400 ℃(CRM). Cu, Mn, Co, Ni, and Zn were used as the transition metals for the modified CRM catalyst. The physical and chemical properties of each catalyst were investigated by BET, SEM, XRD, TPR and FTIR analysis. The transition metals improved the reaction activity of CRM. The order of activation of each catalyst according to transition metals was Cu/CRM > Mn/CRM> Co/CRM > Ni/CRM ≥ Zn/CRM > CRM. The activity order of the catalysts was associated with the mobility of the lattice oxygen of the catalyst. In addition, the catalytic activity with respect to the VOC molecule (benzene, toluene, and xylene) was related to the ionization potential energy of the aromatic compound.
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      Red mud(RM), a byproduct of alumina production, was incorporated with a transition metal, which was used as a catalyst for oxidation of volatile organic compounds (VOCs). RM was treated with hydrochloric acid and ammonia and then calcined at 400 ℃(C...

      Red mud(RM), a byproduct of alumina production, was incorporated with a transition metal, which was used as a catalyst for oxidation of volatile organic compounds (VOCs). RM was treated with hydrochloric acid and ammonia and then calcined at 400 ℃(CRM). Cu, Mn, Co, Ni, and Zn were used as the transition metals for the modified CRM catalyst. The physical and chemical properties of each catalyst were investigated by BET, SEM, XRD, TPR and FTIR analysis. The transition metals improved the reaction activity of CRM. The order of activation of each catalyst according to transition metals was Cu/CRM > Mn/CRM> Co/CRM > Ni/CRM ≥ Zn/CRM > CRM. The activity order of the catalysts was associated with the mobility of the lattice oxygen of the catalyst. In addition, the catalytic activity with respect to the VOC molecule (benzene, toluene, and xylene) was related to the ionization potential energy of the aromatic compound.

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      참고문헌 (Reference)

      1 남승원, "휘발성 유기화합물 완전산화에 대한 폐 Pd촉매 및 폐 Cu촉매의 촉매 활성: 고온가스 처리 효과" 한국환경기술학회 12 (12): 156-166, 2011

      2 Cordi, E. M., "Transient oxidation of volatile organic compounds on CuO/Al2O3catalyst" 14 : 23-36, 1997

      3 Alp, A., "The influence of soda additive on the thermal properties of red mud" 73 : 201-207, 2003

      4 Kim, S. C., "The catalytic oxidation of aromatic hydrocarbons over supported metal oxide" B91 : 285-299, 2002

      5 Yuan, B., "Synergetic dispersion effect of graphene nanohybrid on the thermal stabilityand mechanical properties of ethylene vinyl acetate copolymernanocomposite" 53 : 1143-1149, 2014

      6 Gric, B., "Structure sensitivity of dimethylamine deep oxidation over Pt/Al2O3 catalysts" 90 : 478-484, 2009

      7 Ruddy, E. N., "Select the best VOC control strategy" 89 : 28-35, 1993

      8 심왕근, "Recycling of red mud as a catalyst for complete oxidation of benzene" 한국공업화학회 60 : 259-267, 2018

      9 Kim, S. C., "Property and performance of red mud-based catalysts for the complete oxidation of volatile organic compounds" 300 : 104-113, 2015

      10 Wang, C. H., "Performance of the supported copper oxide catalysts for the catalytic incineration of aromatic hydrocarbons" 64 : 503-509, 2006

      1 남승원, "휘발성 유기화합물 완전산화에 대한 폐 Pd촉매 및 폐 Cu촉매의 촉매 활성: 고온가스 처리 효과" 한국환경기술학회 12 (12): 156-166, 2011

      2 Cordi, E. M., "Transient oxidation of volatile organic compounds on CuO/Al2O3catalyst" 14 : 23-36, 1997

      3 Alp, A., "The influence of soda additive on the thermal properties of red mud" 73 : 201-207, 2003

      4 Kim, S. C., "The catalytic oxidation of aromatic hydrocarbons over supported metal oxide" B91 : 285-299, 2002

      5 Yuan, B., "Synergetic dispersion effect of graphene nanohybrid on the thermal stabilityand mechanical properties of ethylene vinyl acetate copolymernanocomposite" 53 : 1143-1149, 2014

      6 Gric, B., "Structure sensitivity of dimethylamine deep oxidation over Pt/Al2O3 catalysts" 90 : 478-484, 2009

      7 Ruddy, E. N., "Select the best VOC control strategy" 89 : 28-35, 1993

      8 심왕근, "Recycling of red mud as a catalyst for complete oxidation of benzene" 한국공업화학회 60 : 259-267, 2018

      9 Kim, S. C., "Property and performance of red mud-based catalysts for the complete oxidation of volatile organic compounds" 300 : 104-113, 2015

      10 Wang, C. H., "Performance of the supported copper oxide catalysts for the catalytic incineration of aromatic hydrocarbons" 64 : 503-509, 2006

      11 Becker, L., "Oxidative decomposition of benzene and its methyl derivatives catalyzed by copper and palladium ion-exchanged Y-type zeolites" 17 : 43-49, 1998

      12 Wang, S., "Novel applications of red mud as coagulant, adsorbent and catalyst for environmentally benign processes" 72 : 1621-1635, 2008

      13 Grbic, B., "Kinetics of deep oxidation of n-hexane and toluene over Pt/Al2O3catalysts : oxidation of mixture" 50 : 161-166, 2004

      14 Rochester, C. H., "Infrared study of surface hydroxyl groups on haematite" 75 : 1073-1078, 1979

      15 Pratt, K. C., "Hydrogenation of a model hydrogen-donor system using activated red mud catalyst" 61 : 460-466, 1982

      16 Shim, W. G., "Heterogeneous adsorption and catalytic oxidation of benzene, toluene andxylene over spent and chemically regenerated platinum catalyst supportedon activated carbon" 256 : 5566-5571, 2010

      17 Shim, W. G., "Evaluation of regeneration of spent three-way catalysts for catalytic oxidation of aromatic hydrocarbons" 164 : 500-506, 2011

      18 Li, Y., "Effect of the pressure on the catalytic oxidation of volatile organic compounds over Ag/Al2O3catalyst" 89 : 659-664, 2009

      19 Lamallem, M., "Effect of the preparation method on Au/Ce-Ti-O catalysts activity for VOCs oxidation" 137 : 367-372, 2008

      20 Garcia, T., "Deep oxidation of light alkanes over titania-supported palladium/vanadium catalysts" 229 : 1-11, 2005

      21 An, N., "Complete oxidation of formaldehyde at ambient temperature over supported Pt/Fe2O3 catalysts prepared by colloid-deposition method" 186 : 1392-1397, 2011

      22 Tsou, J., "Catalytic oxidation of volatile organic compounds : Oxidation of methyl-isobutyl-ketone over Pt/zeolite catalysts" 57 : 117-123, 2005

      23 Everaert, K., "Catalytic combustion of volatile organic compounds" 109 : 113-139, 2004

      24 Scire, C., "Catalytic combustion of `volatile organic compounds over group IB metal catalysts on Fe2O3" 2 : 229-232, 2001

      25 Kim, S. C., "Catalytic combustion of VOCs over a series of manganese oxide catalysts" 98 : 180-185, 2010

      26 Sushil, S., "Catalytic applications of red mud, an aluminium industry waste: A review" 81 : 64-77, 2008

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      2013-01-01 평가 등재후보 1차 FAIL (등재후보1차) KCI등재후보
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