<P>A new color-tunable Eu<SUP>2+</SUP>-doped sodium aluminium silicate, Na<SUB>2−<I>x</I>−<I>y</I></SUB>Al<SUB>2−<I>x</I></SUB>Si<SUB><I>x</...
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https://www.riss.kr/link?id=A107659897
2012
-
SCI,SCIE,SCOPUS
학술저널
5374-5381(8쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<P>A new color-tunable Eu<SUP>2+</SUP>-doped sodium aluminium silicate, Na<SUB>2−<I>x</I>−<I>y</I></SUB>Al<SUB>2−<I>x</I></SUB>Si<SUB><I>x</...
<P>A new color-tunable Eu<SUP>2+</SUP>-doped sodium aluminium silicate, Na<SUB>2−<I>x</I>−<I>y</I></SUB>Al<SUB>2−<I>x</I></SUB>Si<SUB><I>x</I></SUB>O<SUB>4</SUB>:<I>y</I>Eu<SUP>2+</SUP> (0 ≤<I>x</I>≤ 1), phosphor system was investigated as a novel candidate for phosphor-converted white light-emitting diode (LED) applications and successfully synthesized by wet chemical methods based on the hydrolysis of tetraethyl orthosilicate (TEOS). Different crystal structures and emission spectra were obtained by varying the ratio of Al to Si in the phosphor Na<SUB>2−<I>x</I></SUB>Al<SUB>2−<I>x</I></SUB>Si<SUB><I>x</I></SUB>O<SUB>4</SUB> with <I>x</I> value ranging from 0.25 to 0.55. The Na<SUB>2−<I>x</I>−<I>y</I></SUB>Al<SUB>2−<I>x</I></SUB>Si<SUB><I>x</I></SUB>O<SUB>4</SUB>:<I>y</I>Eu<SUP>2+</SUP> phosphor system emitted a maximum intensity at 470–600 nm when using a 395 nm excitation wavelength, and the emission was strongly affected by the crystal structures determined by the <I>x</I> value. Substitution of Eu<SUP>2+</SUP> affected the center wavelength and emission intensity due to changes in the crystal-field effect, which was strongly dependent on the crystal structure. The LED device exhibited an excellent color-rendering index <I>R</I><SUB>a</SUB> of 93 at a correlated color temperature of 4258 K with CIE color coordinates of (0.3629, 0.3427) under a 20 mA forward-bias current. Based on these results, we are currently evaluating the potential application of Na<SUB>2−<I>x</I>−<I>y</I></SUB>Al<SUB>2−<I>x</I></SUB>Si<SUB><I>x</I></SUB>O<SUB>4</SUB>:<I>y</I>Eu<SUP>2+</SUP> as a white-emitting UV-convertible phosphor.</P>
<P>Graphic Abstract</P><P>A new color-tunable Eu<SUP>2+</SUP>-doped sodium aluminium silicate, Na<SUB>2−<I>x</I></SUB>Al<SUB>2−<I>x</I></SUB>Si<SUB><I>x</I></SUB>O<SUB>4</SUB> (0 ≤<I>x</I>≤ 1), phosphor system and dependency of its photoluminescence on the three different crystal structures (<I>x</I> value).
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Luminescence characteristics and site-occupancy of Eu2+- and Eu3+-doped MgZn2(PO4)2 phosphors