Near‐infrared (NIR) organic solid‐state lasers play an essential role in applications ranging from laser communication to infrared night vision, but progress in this area is restricted by the lack of effective excited‐state gain processes. Herei...
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https://www.riss.kr/link?id=O112474260
2021년
-
1433-7851
1521-3773
SCI;SCIE;SCOPUS
학술저널
9114-9119 [※수록면이 p5 이하이면, Review, Columns, Editor's Note, Abstract 등일 경우가 있습니다.]
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
Near‐infrared (NIR) organic solid‐state lasers play an essential role in applications ranging from laser communication to infrared night vision, but progress in this area is restricted by the lack of effective excited‐state gain processes. Herei...
Near‐infrared (NIR) organic solid‐state lasers play an essential role in applications ranging from laser communication to infrared night vision, but progress in this area is restricted by the lack of effective excited‐state gain processes. Herein, we originally proposed and demonstrated the cascaded occurrence of excited‐state intramolecular proton transfer for constructing the completely new energy‐level systems. Cascading by the first ultrafast proton transfer of <430 fs and the subsequent irreversible second proton transfer of ca. 1.6 ps, the stepwise proton transfer process favors the true six‐level photophysical cycle, which supports efficient population inversion and thus NIR single‐mode lasing at 854 nm. This work realizes longest wavelength beyond 850 nm of organic single‐crystal lasing to date and originally exploits the cascaded excited‐state molecular proton transfer energy‐level systems for organic solid‐state lasers.
Six‐level energy systems are constructed through the cascaded occurrence of excited‐state intramolecular proton transfer consisting of a first ultrafast proton transfer of <430 fs and a following dominant and irreversible proton transfer of ca. 1.6 ps, which support the NIR single‐mode lasing at 854 nm for exploiting energy‐level systems of OSSLs, especially at the NIR region from 780 to 2500 nm.
Graphical Abstract: Angew. Chem. Int. Ed. 16/2021