<P>Naphthalene diimide (NDI)-based conjugated polymers with bithiophene or dithienylethene (TVT) units can form large crystal domains through NDI-driven self-assembly and are widely used in organic electronic devices as n-type materials. However...
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https://www.riss.kr/link?id=A107702819
2019
-
SCOPUS,SCIE
학술저널
4864-4872(9쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<P>Naphthalene diimide (NDI)-based conjugated polymers with bithiophene or dithienylethene (TVT) units can form large crystal domains through NDI-driven self-assembly and are widely used in organic electronic devices as n-type materials. However...
<P>Naphthalene diimide (NDI)-based conjugated polymers with bithiophene or dithienylethene (TVT) units can form large crystal domains through NDI-driven self-assembly and are widely used in organic electronic devices as n-type materials. However, improving electron transport in these semiconducting polymers has been a significant challenge mainly due to poor electrical connections between the crystal domains. Formation of an interconnected network of small domains with short-range ordering and mixed orientations could be an effective way of increasing the electron mobility (μ<SUB>e</SUB>) of polymeric materials. The present study demonstrates the feasibility of this approach using an NDI-based polymer composed of fluorinated TVT (FTVT) units. The FTVT unit enhances intermolecular interactions between the polymer chains, leading to robust aggregation. This aggregation was found to suppress NDI-driven self-assembly, resulting in interconnected small crystal domains with short-range ordering and good thermal stability at elevated temperatures. This microstructure provided transistor devices with improved μ<SUB>e</SUB> by lowering energetic disorder as well as consistent electrical connectivity at different annealing temperatures.</P>
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