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      고분자 전해질 연료전지용 술폰화된 폴리(아릴렌 이써 설폰)/ SPVdF-co-HFP 브렌딩 멤브레인의 제조 및 특성 분석 = Preparation and Characterization of SPAES/SPVdF-co-HFP Blending Membranes for Polymer Electrolyte Membrane Fuel Cells

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      https://www.riss.kr/link?id=A107366372

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      다국어 초록 (Multilingual Abstract)

      In this work, preparation and characterizations of hybrid membranes containing sulfonated poly(arylene ether sulfone) (SPES) and sulfonated poly(vinylidene fluoride-co-hexafluoropropylene) (SPVdF-co-HFP) (20, 30 or 40 wt%) were carried out. The struct...

      In this work, preparation and characterizations of hybrid membranes containing sulfonated poly(arylene ether sulfone) (SPES) and sulfonated poly(vinylidene fluoride-co-hexafluoropropylene) (SPVdF-co-HFP) (20, 30 or 40 wt%) were carried out. The structure of hybrid membranes was confirmed using X-ray diffraction (XRD) analysis and the Fourier transform infrared (FT-IR) spectroscopy. The prepared SPAES/SPVdF-30 membrane exhibits higher ionic conductivity of 68.9 mS/cm at 90℃ and 100% RH. Besides, the other studies showed that the hybrid membrane has good oxidation stability, thermal stability, and mechanical stability. Thus, we believe that the prepared hybrid membrane is suitable for the development of membranes for fuel cell applications.

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      참고문헌 (Reference)

      1 Mohanraj Vinothkannan, "Toward improved mechanical strength, oxidative stability and proton conductivity of an aligned quadratic hybrid (SPEEK/FPAPB/Fe 3 O 4 -FGO) membrane for application in high temperature and low humidity fuel cells" Royal Society of Chemistry (RSC) 7 (7): 39034-39048, 2017

      2 Aylin Rahnavard, "The effect of sulfonated poly (ether ether ketone) as the electrode ionomer for self-humidifying nanocomposite proton exchange membrane fuel cells" Elsevier BV 82 : 746-757, 2015

      3 Chengji Zhao, "Synthesis of the block sulfonated poly(ether ether ketone)s (S-PEEKs) materials for proton exchange membrane" Elsevier BV 280 (280): 643-650, 2006

      4 Kwangjin Oh, "Synthesis of sulfonated poly(arylene ether ketone) block copolymers for proton exchange membrane fuel cells" Elsevier BV 507 : 135-142, 2016

      5 Boping Zhang, "Synthesis and properties of reprocessable sulfonated polyimides cross-linked via acid stimulation for use as proton exchange membranes" Elsevier BV 337 : 110-117, 2017

      6 Takefumi Mikami, "Synthesis and properties of multiblock copoly(arylene ether)s containing superacid groups for fuel cell membranes" Wiley 49 (49): 452-464, 2011

      7 Huixiong Xie, "Synthesis and properties of highly branched star-shaped sulfonated block poly(arylene ether)s as proton exchange membranes" Elsevier BV 473 : 226-236, 2015

      8 Yuan Zhao, "Synthesis and evaluation of all-block-sulfonated copolymers as proton exchange membranes for fuel cell application" Elsevier BV 351 (351): 28-35, 2010

      9 Young-Don Lim, "Synthesis and characterization of sulfonated poly (arylene ether ketone sulfone) block copolymers containing multi-phenyl for PEMFC" Elsevier BV 38 (38): 631-639, 2013

      10 Ji Young Chu, "Synthesis and characterization of partially fluorinated sulfonated poly(arylene biphenylsulfone ketone) block copolymers containing 6F-BPA and perfluorobiphenylene units" Elsevier BV 38 (38): 6268-6274, 2013

      1 Mohanraj Vinothkannan, "Toward improved mechanical strength, oxidative stability and proton conductivity of an aligned quadratic hybrid (SPEEK/FPAPB/Fe 3 O 4 -FGO) membrane for application in high temperature and low humidity fuel cells" Royal Society of Chemistry (RSC) 7 (7): 39034-39048, 2017

      2 Aylin Rahnavard, "The effect of sulfonated poly (ether ether ketone) as the electrode ionomer for self-humidifying nanocomposite proton exchange membrane fuel cells" Elsevier BV 82 : 746-757, 2015

      3 Chengji Zhao, "Synthesis of the block sulfonated poly(ether ether ketone)s (S-PEEKs) materials for proton exchange membrane" Elsevier BV 280 (280): 643-650, 2006

      4 Kwangjin Oh, "Synthesis of sulfonated poly(arylene ether ketone) block copolymers for proton exchange membrane fuel cells" Elsevier BV 507 : 135-142, 2016

      5 Boping Zhang, "Synthesis and properties of reprocessable sulfonated polyimides cross-linked via acid stimulation for use as proton exchange membranes" Elsevier BV 337 : 110-117, 2017

      6 Takefumi Mikami, "Synthesis and properties of multiblock copoly(arylene ether)s containing superacid groups for fuel cell membranes" Wiley 49 (49): 452-464, 2011

      7 Huixiong Xie, "Synthesis and properties of highly branched star-shaped sulfonated block poly(arylene ether)s as proton exchange membranes" Elsevier BV 473 : 226-236, 2015

      8 Yuan Zhao, "Synthesis and evaluation of all-block-sulfonated copolymers as proton exchange membranes for fuel cell application" Elsevier BV 351 (351): 28-35, 2010

      9 Young-Don Lim, "Synthesis and characterization of sulfonated poly (arylene ether ketone sulfone) block copolymers containing multi-phenyl for PEMFC" Elsevier BV 38 (38): 631-639, 2013

      10 Ji Young Chu, "Synthesis and characterization of partially fluorinated sulfonated poly(arylene biphenylsulfone ketone) block copolymers containing 6F-BPA and perfluorobiphenylene units" Elsevier BV 38 (38): 6268-6274, 2013

      11 Ahmad Akbari, "Sulfonation and mixing with TiO2 nanoparticles as two simultaneous solutions for reducing fouling of polysulfone loose nanofiltration membrane" 한국화학공학회 33 (33): 2439-2452, 2016

      12 Ahmad Bagheri, "Sulfonated poly(etheretherketone) and sulfonated polyvinylidene fluoride-co-hexafluoropropylene based blend proton exchange membranes for direct methanol fuel cell applications" Royal Society of Chemistry (RSC) 6 (6): 39500-39510, 2016

      13 Taeyun Ko, "Sulfonated poly(arylene ether sulfone) composite membranes having poly(2,5-benzimidazole)-grafted graphene oxide for fuel cell applications" Royal Society of Chemistry (RSC) 3 (3): 20595-20606, 2015

      14 Ae Rhan Kim, "Sulfonated fluorinated multi-block copolymer hybrid containing sulfonated(poly ether ether ketone) and graphene oxide: A ternary hybrid membrane architecture for electrolyte applications in proton exchange membrane fuel cells" Elsevier BV 27 (27): 1247-1260, 2018

      15 Ae Rhan Kim, "Sulfonated fluorinated block copolymer containing naphthalene unit/sulfonated polyvinylidene-co-hexafluoropropylene/functionalized silicon dioxide ternary composite membrane for low-humidity fuel cell applications" Springer Science and Business Media LLC 296 (296): 1891-1903, 2018

      16 Elif Erdal Unveren, "Role of post-sulfonation of poly(ether ether sulfone) in proton conductivity and chemical stability of its proton exchange membranes for fuel cell" Elsevier BV 35 (35): 3736-3744, 2010

      17 S. J. Peighambardoust, "Review of the proton exchange membranes for fuel cell applications" 35 (35): 9349-9384, 2010

      18 Lakshmi Unnikrishnan, "Proton exchange membranes from sulfonated poly(ether ether ketone) reinforced with silica nanoparticles" SAGE Publications 25 (25): 854-867, 2013

      19 Byeong Hun Oh, "Profile of extended chemical stability and mechanical integrity and high hydroxide ion conductivity of poly(ether imide) based membranes for anion exchange membrane fuel cells" Elsevier BV 44 (44): 4281-4292, 2019

      20 Seung-Hee Park, "Preparation of organic/inorganic composite membranes using two types of polymer matrix via a sol–gel process" Elsevier BV 181 (181): 259-266, 2008

      21 Taehyun Yoo, "Modified sulfonated Poly(arylene ether) multiblock copolymers containing highly sulfonated blocks for polymer electrolyte membrane fuel cells" Elsevier BV 542 : 102-109, 2017

      22 Jochen Meier-Haack, "Membranes from sulfonated block copolymers for use in fuel cells" Elsevier BV 41 (41): 207-220, 2005

      23 Yoshimitsu Sakaguchi, "Isomeric effect of sulfonated poly(arylene ether)s comprising dihydroxynaphthalene on properties for polymer electrolyte membranes" Wiley 50 (50): 4749-4755, 2012

      24 Kanagaraj Selvakumar, "Investigation on meta-polybenzimidazole blend with sulfonated PVdF-HFP proton conducting polymer electrolytes for HT-PEM fuel cell application" Springer Science and Business Media LLC 29 (29): 15163-15173, 2018

      25 E. Annika Weiber, "Highly Proton Conducting Electrolyte Membranes Based on Poly(arylene sulfone)s with Tetrasulfonated Segments" American Chemical Society (ACS) 46 (46): 3476-3485, 2013

      26 Aruna K. Mohanty, "Highly Fluorinated Sulfonated Poly(arylene ether sulfone) Copolymers: Synthesis and Evaluation of Proton Exchange Membrane Properties" American Chemical Society (ACS) 52 (52): 2772-2783, 2013

      27 Elin Persson Jutemar, "Facile Synthesis and Polymerization of 2,6-Difluoro-2′-sulfobenzophenone for Aromatic Proton Conducting Ionomers with Pendant Sulfobenzoyl Groups" Wiley 31 (31): 1348-1353, 2010

      28 Hai Qiang Li, "Enhanced proton conductivity of sulfonated poly(arylene ether ketone sulfone) for fuel cells by grafting triazole groups onto polymer chains" Elsevier BV 509 : 173-181, 2016

      29 Kyu Ha Lee, "Enhanced Performance of a Sulfonated Poly(arylene ether ketone) Block Copolymer Bearing Pendant Sulfonic Acid Groups for Polymer Electrolyte Membrane Fuel Cells Operating at 80% Relative Humidity" American Chemical Society (ACS) 10 (10): 20835-20844, 2018

      30 Byungchan Bae, "Effect of the Hydrophobic Component on the Properties of Sulfonated Poly(arylene ether sulfone)s" American Chemical Society (ACS) 42 (42): 1873-1880, 2009

      31 Balappa B. Munavalli, "Development of novel sulfonic acid functionalized zeolites incorporated composite proton exchange membranes for fuel cell application" Elsevier BV 296 : 294-307, 2019

      32 Gilles P. Robertson, "Casting solvent interactions with sulfonated poly(ether ether ketone) during proton exchange membrane fabrication" Elsevier BV 219 (219): 113-121, 2003

      33 Ae Rhan Kim, "Amelioration in physicochemical properties and single cell performance of sulfonated poly(ether ether ketone) block copolymer composite membrane using sulfonated carbon nanotubes for intermediate humidity fuel cells" Wiley 43 (43): 2974-2989, 2019

      34 Michael A. Hickner, "Alternative Polymer Systems for Proton Exchange Membranes (PEMs)" American Chemical Society (ACS) 104 (104): 4587-4612, 2004

      35 Ae Kim, "Alleviating the Mechanical and Thermal Degradations of Highly Sulfonated Poly(Ether Ether Ketone) Blocks via Copolymerization with Hydrophobic Unit for Intermediate Humidity Fuel Cells" MDPI AG 10 (10): 1346-, 2018

      36 Megan E. Scofield, "A concise guide to sustainable PEMFCs: recent advances in improving both oxygen reduction catalysts and proton exchange membranes" Royal Society of Chemistry (RSC) 44 (44): 5836-5860, 2015

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