<P>We designed and synthesized a novel conjugated polyelectrolyte (CPE), poly{3-[2-[4,8-bis(2-ethyl-hexyloxy)-6-methyl-1,5-dithia-<I>s</I>-indacen-2-yl]-9-(3-dimethylamino-propyl)-7-methyl-9H-fluoren-9-yl]-propyl}-dimethyl-amine (PBN...
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https://www.riss.kr/link?id=A107603754
2014
-
SCOPUS,SCIE
학술저널
15875-15880(6쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<P>We designed and synthesized a novel conjugated polyelectrolyte (CPE), poly{3-[2-[4,8-bis(2-ethyl-hexyloxy)-6-methyl-1,5-dithia-<I>s</I>-indacen-2-yl]-9-(3-dimethylamino-propyl)-7-methyl-9H-fluoren-9-yl]-propyl}-dimethyl-amine (PBN...
<P>We designed and synthesized a novel conjugated polyelectrolyte (CPE), poly{3-[2-[4,8-bis(2-ethyl-hexyloxy)-6-methyl-1,5-dithia-<I>s</I>-indacen-2-yl]-9-(3-dimethylamino-propyl)-7-methyl-9H-fluoren-9-yl]-propyl}-dimethyl-amine (PBN). We employed PBN as an electron-transporting layer on a ZnO layer and constructed a highly efficient, inverted structure device consisting of a mixture of poly({4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-<I>b</I>:4,5-<I>b</I>′]dithiophene-2,6-diyl}{3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-<I>b</I>]thiophenediyl}) (PTB7) and PC<SUB>70</SUB>BM, achieving a high power conversion of up to 8.6%, constituting a 21.1% improvement over the control device performance (7.1%) prepared without a PBN layer. This result was ascribed to the reduced interfacial resistance and the improved charge transport and collection through the PBN electron transport layer.</P><P><B>Graphic Abstract</B>
<IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/aamick/2014/aamick.2014.6.issue-18/am503419r/production/images/medium/am-2014-03419r_0001.gif'></P><P><A href='http://pubs.acs.org/doi/suppl/10.1021/am503419r'>ACS Electronic Supporting Info</A></P>
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