Carbon nanotubes-properties and applications: a review

다국어 초록 (Multilingual Abstract)

The carbon nanotube (CNT) represents one of the most unique inventions in the field of nanotechnology. CNTs have been studied closely over the last two decades by many researchers around the world due to their great potential in different fields. CNTs are rolled graphene with SP2 hybridization. The important aspects of CNTs are their light weight, small size with a high aspect ratio, good tensile strength, and good conducting characteristics, which make them useful as fillers in different materials such as polymers, metallic surfaces and ceramics. CNTs also have potential applications in the field of nanotechnology, nanomedicine, transistors, actuators, sensors, membranes, and capacitors. There are various techniques which can be used for the synthesis of CNTs. These include the arc-discharge method, chemical vaporize deposition (CVD), the laser ablation method, and the sol gel method. CNTs can be single-walled, double-walled and multi-walled. CNTs have unique mechanical, electrical and optical properties, all of which have been extensively studied. The present review is focused on the synthesis, functionalization, properties and applications of CNTs. The toxic effect of CNTs is also presented in a summarized form.

참고문헌 (Reference)

1 Sheshmania S, "Wood plastic composite using graphene nanoplatelets" 58 : 6-, 2013

2 Simeonova PP, "Update on carbon nanotube toxicity" 4 : 373-, 2009

3 Rinzler AG, "Unraveling nanotubes: field emission from an atomic wire" 269 : 1550-, 1995

4 Nemmar A, "Ultrafine particles affect experimental thrombosis in an in vivo hamster model" 166 : 998-, 2002

5 Evanoff K, "Ultra strong silicon-coated carbon nanotube nonwoven fabric as a multifunctional lithium-ion battery anode" 6 : 9837-, 2012

6 Prasher RS, "Turning carbon nanotubes from exceptional heat conductors into insulators" 102 : 105901-, 2009

7 Saether E, "Transverse mechanical properties of single walled carbon nanotube crystals. Part I: determination of elastic moduli" 63 : 1543-, 2003

8 Kim P, "Thermal transport measurements of individual multiwalled nanotubes" 87 : 215502-, 2001

9 Yu C, "Thermal conductance and thermopower of an individual single-wall carbon nanotube" 5 : 1842-, 2005

10 Popov VN, "Theoretical evidence for T1/2 specific heat behavior in carbon nanotube systems" 42 : 991-, 2004

11 Gadd GE, "The world’s smallest gas cylinders?" 277 : 933-, 1997

12 Vaisman L, "The role of surfactants in dispersion of carbon nanotubes" 128-130 : 37-, 2006

13 Geim AK, "The rise of graphene" 6 : 183-, 2007

14 Lau AKT, "The revolutionary creation of new advanced materials--carbon nanotube composites" 33 : 263-, 2002

15 Rotman D, "The nanotube computer" 105 : 36-, 2002

16 Sydlik U, "The compatible solute ectoine protects against nanoparticleinduced neutrophilic lung inflammation" 180 : 29-, 2009

17 Li F, "Tensile strength of single-walled carbon nanotubes directly measured from their macroscopic ropes" 77 : 3161-, 2000

18 Yu MF, "Tensile loading of ropes of single wall carbon nanotubes and their mechanical properties" 84 : 5552-, 2000

19 Garcia-Gutierrez MC, "Templating of crystallization and shear-induced self-assembly of single-wall carbon nanotubes in a polymer-nanocomposite" 47 : 341-, 2006

20 Satishkumar BC, "Synthesis of metal oxide nanorods using carbon nanotubes as templates" 10 : 2115-, 2000

21 Jurewicz K, "Supercapacitors from nanotubes/polypyrrole composites" 347 : 36-, 2001

22 Overney G, "Structural rigidity and low frequency vibrational modes of long carbon tubules" 27 : 93-, 1993

23 Iijima S, "Structural flexibility of carbon nanotubes" 104 : 2089-, 1996

24 Fenoglio I, "Structural defects play a major role in the acute lung toxicity of multiwall carbon nanotubes: physicochemical aspects" 21 : 1690-, 2008

25 Yu MF, "Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load" 287 : 637-, 2000

26 Ashcroft NW, "Solid State Physics" Harcourt Brace 1976

27 Kasuya A, "Size dependent characteristics of single wall carbon nanotubes" 217-218 : 46-, 1996

28 Wood JR, "Single-wall carbon nanotubes as molecular pressure sensors" 76 : 2883-, 2000

29 Iijima S, "Single-shell carbon nanotubes of 1-nm diameter" 363 : 603-, 1993

30 Dresselhaus MS, "Science of Fullerenes and Carbon Nanotubes" Academic Press 1996

31 Oberdorster G, "Safety assessment for nanotechnology and nanomedicine: concepts of nanotoxicology" 267 : 89-, 2010

32 Tans SJ, "Room-temperature transistor based on a single carbon nanotube" 393 : 49-, 1998

33 Helland A, "Reviewing the environmental and human health knowledge base of carbon nanotubes" 115 : 1125-, 2007

34 Saeed K, "Review on the properties, dispersion and toxicology of carbon nanotubes" 32 : 561-, 2010

35 Meregalli V, "Review of theoretical calculations of hydrogen storage in carbon-based materials" 72 : 143-, 2001

36 Darkrim FL, "Review of hydrogen storage by adsorption in carbon nanotubes" 27 : 193-, 2002

37 Minary-Jolandan M, "Reversible radial deformation up to the complete flattening of carbon nanotubes in nanoindentation" 103 : 073516-, 2008

38 Fan-Long Jin, "Recent Advances in Carbon-Nanotube-Based Epoxy Composites" 한국탄소학회 14 (14): 1-13, 2013

39 Yang YH, "Radial elasticity of single-walled carbon nanotube measured by atomic force microscopy" 98 : 041901-, 2011

40 Palaci I, "Radial elasticity of multiwalled carbon nanotubes" 94 : 175502-, 2005

41 Ruoff RS, "Radial deformation of carbon nanotubes by van der Waals forces" 364 : 514-, 1993

42 Delaney P, "Quantized conductance of multiwalled carbon nanotubes" 75 : 3787-, 1999

43 Endo M, "Pyrolytic carbon nanotubes from vapor-grown carbon fibers" 33 : 873-, 1995

44 Kayat J, "Pulmonary toxicity of carbon nanotubes: a systematic report" 7 : 40-, 2011

45 Hersam MC, "Progress towards monodisperse single-walled carbon nanotubes" 3 : 387-, 2008

46 Ma RZ, "Processing and performance of electric double-layer capacitors with blocktype carbon nanotube electrodes" 72 : 2563-, 1999

47 Dai H, "Probing electrical transport in nanomaterials: conductivity of individual carbon nanotubes" 272 : 523-, 1996

48 Saeed K, "Preparation of multiwalled carbon nanotube/ nylon-6 nanocomposites by in situ polymerization" 106 : 3729-, 2007

49 Kar S, "Potential of carbon nanotubes in water purification: an approach towards the development of an integrated membrane system" 3 : 143-, 2008

50 Zhang XX, "Poly(adipic acid-hexamethylene diamine)-functionalized multi-walled carbon nanotube nanocomposites" 46 : 923-, 2011

51 Maeda T, "Phonon modes in single-wall nanotubes with a small diameter" 263-264 : 479-, 1999

52 Maultzsch J, "Phonon dispersion of carbon nanotubes" 121 : 471-, 2002

53 Nemmar A, "Passage of intratracheally instilled ultrafine particles from the lung into the systemic circulation in hamster" 164 : 1665-, 2001

54 Georgakilas V, "Organic functionalization of carbon nanotubes" 124 : 760-, 2002

55 Taniguchi N, "On the basic concept of ‘nano-technology’" 1974

56 Radushkevich LV, "O strukture ugleroda, obrazujucegosja pri termiceskom razlozenii okisi ugleroda na zeleznom kontakte (About the structure of carbon formed by thermal decomposition of carbon monoxide on iron substrate)" 26 : 88-, 1952

57 Terrones M, "Novel nanoscale gas containers: encapsulation of N2 in CNx nanotubes" 23 : 2335-, 2000

58 Bandaru PR, "Novel electrical switching behaviour and logic in carbon nanotube Y-junctions" 4 : 663-, 2005

59 Choi YM, "Nonlinear behavior in the thermopower of doped carbon nanotubes due to strong, localized states" 3 : 839-, 2003

60 Dresselhaus MS, "Nanowires and nanotubes" 23 : 129-, 2003

61 Dai H, "Nanotubes as nanoprobes in scanning probe microscopy" 384 : 147-, 1996

62 Rao CNR, "Nanotubes and nanowires" 59 : 4665-, 2004

63 Kim P, "Nanotube nanotweezers" 286 : 2148-, 1999

64 Stern ST, "Nanotechnology safety concerns revisited" 101 : 4-, 2008

65 Mamalis AG, "Nanotechnology and nanostructured materials: trends in carbon nanotubes" 28 : 16-, 2004

66 Franks A, "Nanotechnology" 20 : 1442-, 1987

67 "NANOSAFE 2008"

68 Prashantha K, "Multi-walled carbon nanotube filled polypropylene nanocomposites based on masterbatch route: improvement of dispersion and mechanical properties through PP-g-MA addition" 2 : 735-, 2008

69 Chandra B, "Molecular-scale quantum dots from carbon nanotube heterojunctions" 9 : 1544-, 2009

70 Pichler T, "Molecular nanostructures: carbon ahead" 6 : 332-, 2007

71 Gordon PA, "Molecular modeling of adsorptive energy storage: hydrogen storage in single-walled carbon nanotubes" 38 : 4647-, 1999

72 Modi A, "Miniaturized gas ionization sensors using carbon nanotubes" 424 : 171-, 2003

73 Tanaka H, "Methane adsorption on single-walled carbon nanotube: a density functional theory model" 352 : 334-, 2002

74 Banhart F, "Metal atoms in carbon nanotubes and related nanoparticles" 15 : 4037-, 2001

75 Siochi EJ, "Melt processing of SWCNTpolyimide nanocomposite fibers" 35 : 439-, 2004

76 Yakobson BI, "Mechanical relaxation and “intramolecular plasticity” in carbon nanotubes" 72 : 918-, 1998

77 Sinnott SB, "Mechanical properties of nanotubule fibers and composites determined from theoretical calculations and simulations" 36 : 1-, 1998

78 Ruoff RS, "Mechanical and thermal properties of carbon nanotubes" 33 : 925-, 1995

79 Wang ZL, "Mechanical and electrostatic properties of carbon nanotubes and nanowires" 16 : 3-, 2001

80 Huang Y, "Logic gates and computation from assembled nanowire building blocks" 294 : 1313-, 2001

81 Bachtold A, "Logic circuits with carbon nanotube transistors" 294 : 1317-, 2001

82 Venema LC, "Length control of individual carbon nanotubes by nanostructuring with a scanning tunneling microscope" 71 : 2629-, 1997

83 Ebbesen TW, "Large-scale synthesis of carbon nanotubes" 358 : 220-, 1992

84 Li WZ, "Large-scale synthesis of aligned carbon nanotubes" 274 : 1701-, 1996

85 Journet C, "Large-scale production of single-walled carbon nanotubes by the electric-arc technique" 388 : 756-, 1997

86 Lee CJ, "Large-scale production of aligned carbon nanotubes by the vapor phase growth method" 359 : 109-, 2002

87 Shibutani Y, "Irreversible deformation of carbon nanotubes under bending" 63 : 1262-, 1999

88 Yu MF, "Investigation of the radial deformability of individual carbon nanotubes under controlled indentation force" 85 : 1456-, 2000

89 Shen W, "Investigation of the radial com pression of carbon nanotubes with a scanning probe microscope" 84 : 3634-, 2000

90 Schonenberger C, "Interference and Interaction in multi-wall carbon nanotubes" 69 : 283-, 1999

91 Vittorio O, "Influence of purity and surface oxidation on cytotoxicity of multiwalled carbon nanotubes with human neuroblastoma cells" 5 : 424-, 2009

92 Tong H, "Influence of acid functionalization on the cardiopulmonary toxicity of carbon nanotubes and carbon black particles in mice" 239 : 224-, 2009

93 Tans SJ, "Individual single-wall carbon nanotubes as quantum wires" 386 : 474-, 1997

94 Xia H, "Hydrothermal synthesis of MnO2/ CNT nanocomposite with a CNT core/porous MnO2 sheath hierarchy architecture for supercapacitors" 7 : 33-, 2012

95 Cao A, "Hydrogen storage of dense-aligned carbon nanotubes" 342 : 510-, 2001

96 Liu C, "Hydrogen storage in single-walled carbon nanotubes at room temperature" 286 : 1127-, 1999

97 Chambers A, "Hydrogen storage in graphite nanofibers" 102 : 4253-, 1998

98 Hirscher M, "Hydrogen storage in carbon nanostructures" 330-332 : 654-, 2002

99 박수진, "Hydrogen Storage Behaviors of Carbon Nanotubes/Metal-organic Frameworks-5 Hybrid Composites" 한국탄소학회 10 (10): 19-22, 2009

100 Niu C, "High power electrochemical capacitors based on carbon nanotube electrodes" 70 : 1480-, 1997

101 Chen P, "High H2 uptake by alkali-doped carbon nanotubes under ambient pressure and moderate temperatures" 285 : 91-, 1999

102 Iijima S, "Helical microtubules of graphitic carbon" 354 : 56-, 1991

103 Warheit DB, "Health effects related to nanoparticle exposures: environmental, health and safety considerations for assessing hazards and risks" 120 : 35-, 2008

104 Yue GZ, "Generation of continuous and pulsed diagnostic imaging x-ray radiation using a carbon-nanotube-based fieldemission cathode" 81 : 355-, 2002

105 Varghese OK, "Gas sensing characteristics of multi-wall carbon nanotubes" 81 : 32-, 2001

106 Hirsch A, "Functionalization of single-walled carbon nanotubes" 41 : 1853-, 2002

107 김정환, "Functionalization of Multi-walled Carbon Nanotube by Treatment with Dry Ozone Gas for the Enhanced Dispersion and Adhesion in Polymeric Composites" 한국탄소학회 11 (11): 298-303, 2010

108 Chopra NG, "Fully collapsed carbon nanotubes" 377 : 135-, 1995

109 Bonard JM, "Field-emission-induced luminescence from carbon nanotubes" 81 : 1441-, 1998

110 Hungo Choo, "Fabrication and Applications of Carbon Nanotube Fibers" 한국탄소학회 13 (13): 191-204, 2012

111 Collins PG, "Extreme oxygen sensitivity of electronic properties of carbon nanotubes" 287 : 1801-, 2000

112 Treacy MMJ, "Exceptionally high Young’s modulus observed for individual carbon nanotubes" 381 : 678-, 1996

113 Collins PG, "Engineering carbon nanotubes and nanotube circuits using electrical breakdown" 292 : 706-, 2001

114 Tersoff J, "Energies of fullerenes" 46 : 15546-, 1992

115 Guanghua G, "Energetics, structure, mechanical and vibrational properties of single-walled carbon nanotubes" 9 : 184-, 1998

116 Robertson DH, "Energetics of nanoscale graphitic tubules" 45 : 12592-, 1992

117 Saito R, "Electronic structure of chiral graphene tubules" 60 : 2204-, 1992

118 De Vita A, "Electronic structure at carbon nanotube tips" 68 : 283-, 1999

119 Ishii H, "Electron-phonon coupling effect on quantum transport in carbon nanotubes using time-dependent wave-packet approach" 40 : 249-, 2007

120 Cheng Y, "Electron field emission from carbon nanotubes" 4 : 1021-, 2003

121 Trasobares S, "Electron beam puncturing of carbon nanotube containers for release of stored N2 gas" 22 : 117-, 2001

122 Frackowiak E, "Electrochemical storage of energy in carbon nanotubes and nanostructured carbons" 40 : 1775-, 2002

123 Postma HWC, "Electrical transport through carbon nanotube junctions created by mechanical manipulation" 62 : R10653-, 2000

124 Park JY, "Electrical cutting and nicking of carbon nanotubes using an atomic force microscope" 80 : 4446-, 2002

125 Ebbesen TW, "Electrical conductivity of individual carbon nanotubes" 382 : 54-, 1996

126 Hone J, "Electrical and thermal transport properties of magnetically aligned single wall carbon nanotube films" 77 : 666-, 2000

127 Hernandez E, "Elastic properties of C and BxCyNz composite nanotubes" 80 : 4502-, 1998

128 Ru CQ, "Effect of van der Waals forces on axial buckling of a double- walled carbon nanotube" 87 : 7227-, 2000

129 Bhattacharyya AR, "Effect of encapsulated SWNT on the mechanical properties of melt mixed PA12/SWNT composites" 392 : 28-, 2004

130 Wang H, "Dispersing carbon nanotubes using surfactants" 14 : 364-, 2009

131 Demczyk BG, "Direct mechanical measurement of the tensile strength and elastic modulus of multiwalled carbon nanotubes" 334 : 173-, 2002

132 Thess A, "Crystalline ropes of metallic carbon nanotubes" 273 : 483-, 1996

133 Wong SS, "Covalently functionalized nanotubes as nanometre- sized probes in chemistry and biology" 394 : 52-, 1998

134 Saito Y, "Conical beams from open nanotubes" 389 : 554-, 1997

135 Zhu YQ, "Collapsing carbon nanotubes and diamond formation under shock waves" 287 : 689-, 1998

136 Bethune DS, "Cobalt-catalysed growth of carbon nanotubes with single-atomic-layer walls" 363 : 605-, 1993

137 Shvedova AA, "Close encounters of the small kind: adverse effects of man-made materials interfacing with the nano-cosmos of biological systems" 50 : 63-, 2010

138 Wu HC, "Chemistry of carbon nanotubes in biomedical applications" 20 : 1036-, 2010

139 Wepasnick KA, "Chemical and structural characterization of carbon nanotube surfaces" 396 : 1003-, 2010

140 Chang TE, "Chang TE, Jensen LR, Kisliuk A, Pipes RB, Pyrz R, Sokolov AP. Microscopic mechanism of reinforcement in single-wall carbon nanotube/polypropylene nanocomposite. Polymer, 46, 439(2005)" 46 : 439-, 2005

141 Saito Y, "Cathode ray tube lighting elements with carbon nanotube field emitters" 37 : L346-, 1998

142 Li Z, "Cardiovascular effects of pulmonary exposure to single-wall carbon nanotubes" 115 : 377-, 2007

143 Chopra S, "Carbon-nanotube- based resonant-circuit sensor for ammonia" 80 : 4632-, 2002

144 Wood JR, "Carbon nanotubes: from molecular to macroscopic sensors" 62 : 7571-, 2000

145 Baughman RH, "Carbon nanotubes- -the route toward applications" 297 : 787-, 2002

146 Ahmad A, "Carbon nanotubes, science and technology part (I) structure, synthesis and characterization" 5 : 1-, 2012

147 Poland CA, "Carbon nanotubes introduced into the abdominal cavity of mice show asbestos-like pathogenicity in a pilot study" 3 : 423-, 2008

148 Sugie H, "Carbon nanotubes as electron source in an x-ray tube" 78 : 2578-, 2001

149 Akiladevi D, "Carbon nanotubes (CNTs) production, characterization and its applications" 1 : 187-, 2010

150 Derycke V, "Carbon nanotube inter- and intramolecular logic gates" 1 : 453-, 2001

151 Xie S, "Carbon nanotube arrays" 286 : 11-, 2000

152 Baughman RH, "Carbon nanotube actuators" 284 : 1340-, 1999

153 Javey A, "Carbon Nanotube Transistor Arrays for Multistage Complementary Logic and Ring Oscillators" 2 : 929-, 2002

154 Kroto HW, "C60: buckminsterfullerene" 318 : 162-, 1985

155 Ajayan PM, "Bulk metal and ceramics nanocomposites, In Nanocomposite Science and Technology" Wiley-VCH Verlag GmbH & Co. 1-, 2004

156 김기석, "Bridge effect of carbon nanotubes on the electrical properties of expanded graphite/poly(ethylene terephthalate) nanocomposites" 한국탄소학회 13 (13): 51-55, 2012

157 Blase X, "Boron-mediated growth of long helicity-selected carbon nanotubes" 83 : 5078-, 1999

158 Falvo MR, "Bending and buckling of carbon nanotubes under large strain" 389 : 582-, 1997

159 Wagner FE, "Before striking gold in gold-ruby glass" 407 : 691-, 2000

160 Mintmire JW, "Are fullerene tubules metallic?" 68 : 631-, 1992

161 Lee NS, "Application of carbon nanotubes to field emission displays" 10 : 265-, 2001

162 Ajayan PM, "Aligned carbon nanotube arrays formed by cutting a polymer resin--nanotube composite" 265 : 1212-, 1994

163 Meunier V, "Ab initio investigations of lithium diffusion in carbon nanotube systems" 88 : 075506-, 2002

164 Myung Gwan Hahm, "A review: controlled synthesis of vertically aligned carbon nanotubes" 한국탄소학회 12 (12): 185-193, 2011

165 Lam CW, "A review of carbon nanotube toxicity and assessment of potential occupational and environmental health risks" 36 : 189-, 2006

166 Lee SM, "A hydrogen storage mechanism in single-walled carbon nanotubes" 123 : 5059-, 2001

167 Johnston HJ, "A critical review of the biological mechanisms underlying the in vivo and in vitro toxicity of carbon nanotubes: the contribution of physico-chemical characteristics" 4 : 207-, 2010