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      Dissipation Patterns of Insecticide Sulfoxaflor in Spinach and Korean Cabbage

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      https://www.riss.kr/link?id=A105971533

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      다국어 초록 (Multilingual Abstract)

      The present greenhouse experiment was carried out to study the residues of sulfoxaflor in spinach and Korean cabbage under different pre-harvest application regimes. After 2 times application of with 1 week interval in that day of harvest (0), 3, 7, 14 and 21 days before harvest, and the residue of pesticides was investigated by LC-MS/MS. Matrix-matched calibration curves for sulfoxaflor in both spinach and Korean cabbage yielded good linearity (R<SUP>2</SUP> ≥ 0.9995). The biological half-lives of sulfoxaflor in spinach and Korean cabbage deduced from first order forms of decline (C=3.2539e<SUP>-0.179t</SUP> in spinach and C=1.2432e<SUP>-0.196t</SUP> in Korean cabbage) were 3.87 and 3.54 days, respectively. Pre-harvest residues of sulfoxaflor in spinach at 10-3 days (2.16 mg/kg) and 7-0 days (2.97 mg/kg) were above the EU-MRL (2.0 mg/kg), but within the MFDS value of 3.0 mg/kg. In Korean cabbage, residues at 10-3 days (0.74 mg/kg) and 7-0 days (1.17 mg/kg) were above the MFDS value of 0.3 mg/kg, though below the EU-MRL (6.0 mg/kg). Based on field incurred residues, it’s safe to apply sulfoxaflor to spinach as per MFDS regulation and Korean cabbage at 21-14 or 14-7 days before harvest as per EU regulation.
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      The present greenhouse experiment was carried out to study the residues of sulfoxaflor in spinach and Korean cabbage under different pre-harvest application regimes. After 2 times application of with 1 week interval in that day of harvest (0), 3, 7, 1...

      The present greenhouse experiment was carried out to study the residues of sulfoxaflor in spinach and Korean cabbage under different pre-harvest application regimes. After 2 times application of with 1 week interval in that day of harvest (0), 3, 7, 14 and 21 days before harvest, and the residue of pesticides was investigated by LC-MS/MS. Matrix-matched calibration curves for sulfoxaflor in both spinach and Korean cabbage yielded good linearity (R<SUP>2</SUP> ≥ 0.9995). The biological half-lives of sulfoxaflor in spinach and Korean cabbage deduced from first order forms of decline (C=3.2539e<SUP>-0.179t</SUP> in spinach and C=1.2432e<SUP>-0.196t</SUP> in Korean cabbage) were 3.87 and 3.54 days, respectively. Pre-harvest residues of sulfoxaflor in spinach at 10-3 days (2.16 mg/kg) and 7-0 days (2.97 mg/kg) were above the EU-MRL (2.0 mg/kg), but within the MFDS value of 3.0 mg/kg. In Korean cabbage, residues at 10-3 days (0.74 mg/kg) and 7-0 days (1.17 mg/kg) were above the MFDS value of 0.3 mg/kg, though below the EU-MRL (6.0 mg/kg). Based on field incurred residues, it’s safe to apply sulfoxaflor to spinach as per MFDS regulation and Korean cabbage at 21-14 or 14-7 days before harvest as per EU regulation.

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      참고문헌 (Reference)

      1 손경애, "형태적 특성이 다른 들깻잎, 상추, 케일 중 농약 잔류량 비교" 한국농약과학회 16 (16): 336-342, 2012

      2 전상오, "소면적 재배 작물 들깻잎 중 살충제 Bifenthrin과 Chlorfenapyr의 잔류양상" 한국환경농학회 34 (34): 223-229, 2015

      3 김다솜, "생산단계 참외 중 Metalaxyl-M 및 Flusilazole의 잔류허용기준 설정연구" 한국농약과학회 18 (18): 1-7, 2014

      4 강자군, "살균제 Fludioxonil 및 Metconazole의 밀 부위별 잔류 양상" 한국농약과학회 20 (20): 341-348, 2016

      5 Manuel Arias-Estévez, "The mobility and degradation of pesticides in soils and the pollution of groundwater resources" Elsevier BV 123 (123): 247-260, 2008

      6 Thomas C. Sparks, "Sulfoxaflor and the sulfoximine insecticides: Chemistry, mode of action and basis for efficacy on resistant insects" Elsevier BV 107 (107): 1-7, 2013

      7 Hyung Suk Chung, "Simultaneous determination of sulfoxaflor and its metabolites, X11719474 and X11721061, in brown rice and rice straw after field application using LC-MS/MS" Informa UK Limited 97 (97): 99-111, 2017

      8 Sung-Woo Kim, "Simultaneous detection of sulfoxaflor and its metabolites, X11719474 and X11721061, in lettuce using a modified QuEChERS extraction method and liquid chromatography-tandem mass spectrometry" Wiley 31 (31): e3885-, 2017

      9 SANTE, "SANTE/10478/2018"

      10 Ioannis N. Tsakiris, "Risk assessment for children exposed to DDT residues in various milk types from the Greek market" Elsevier BV 75 : 156-165, 2015

      1 손경애, "형태적 특성이 다른 들깻잎, 상추, 케일 중 농약 잔류량 비교" 한국농약과학회 16 (16): 336-342, 2012

      2 전상오, "소면적 재배 작물 들깻잎 중 살충제 Bifenthrin과 Chlorfenapyr의 잔류양상" 한국환경농학회 34 (34): 223-229, 2015

      3 김다솜, "생산단계 참외 중 Metalaxyl-M 및 Flusilazole의 잔류허용기준 설정연구" 한국농약과학회 18 (18): 1-7, 2014

      4 강자군, "살균제 Fludioxonil 및 Metconazole의 밀 부위별 잔류 양상" 한국농약과학회 20 (20): 341-348, 2016

      5 Manuel Arias-Estévez, "The mobility and degradation of pesticides in soils and the pollution of groundwater resources" Elsevier BV 123 (123): 247-260, 2008

      6 Thomas C. Sparks, "Sulfoxaflor and the sulfoximine insecticides: Chemistry, mode of action and basis for efficacy on resistant insects" Elsevier BV 107 (107): 1-7, 2013

      7 Hyung Suk Chung, "Simultaneous determination of sulfoxaflor and its metabolites, X11719474 and X11721061, in brown rice and rice straw after field application using LC-MS/MS" Informa UK Limited 97 (97): 99-111, 2017

      8 Sung-Woo Kim, "Simultaneous detection of sulfoxaflor and its metabolites, X11719474 and X11721061, in lettuce using a modified QuEChERS extraction method and liquid chromatography-tandem mass spectrometry" Wiley 31 (31): e3885-, 2017

      9 SANTE, "SANTE/10478/2018"

      10 Ioannis N. Tsakiris, "Risk assessment for children exposed to DDT residues in various milk types from the Greek market" Elsevier BV 75 : 156-165, 2015

      11 Suman Gupta, "Residue behavior of combination formulations of insecticides in/on cabbage and their efficacy against aphids and diamondback moth" Springer Nature 187 (187): 4076-, 2015

      12 Gurmail Singh, "Residue Dynamics and Risk Assessment of Trifloxystrobin and Tebuconazole on Tomato (Lycopersicon esculentum Mill.)" Science and Education Publishing Co., Ltd. 2 (2): 59-63, 2014

      13 Belay T. Mengistie, "Pesticide use practices among smallholder vegetable farmers in Ethiopian Central Rift Valley" Springer Nature 19 (19): 301-324, 2017

      14 FAO Panel of Experts on Pesticide Residues in Food and the Environment, "Pesticide residues in food 2011" 2011

      15 Ahmad Hanafi, "Minor crops for export: A case study of boscalid, pyraclostrobin, lufenuron and lambda-cyhalothrin residue levels on green beans and spring onions in Egypt" Informa UK Limited 45 (45): 493-500, 2010

      16 Svetlana Hrouzková, "Investigation of Levels and Fate of Pyridalyl in Fruit and Vegetable Samples by Fast Gas Chromatography–Mass Spectrometry" Springer Nature 6 (6): 969-977, 2013

      17 Zenglong Chen, "Influence of Uptake Pathways on the Stereoselective Dissipation of Chiral Neonicotinoid Sulfoxaflor in Greenhouse Vegetables" American Chemical Society (ACS) 64 (64): 2655-2660, 2016

      18 Jeong-In Hwang, "Improved dissipation kinetic model to estimate permissible pre-harvest residue levels of pesticides in apples" Springer Nature 190 (190): 438-, 2018

      19 Anke Buchholz, "How active ingredient localisation in plant tissues determines the targeted pest spectrum of different chemistries" Wiley 72 (72): 929-939, 2016

      20 Akash Sabarwal, "Hazardous effects of chemical pesticides on human health–Cancer and other associated disorders" Elsevier BV 63 : 103-114, 2018

      21 Butnariu, M, "Handbook of Food Chemistry" Springer Berlin Heidelberg 627-692, 2015

      22 이주영, "HPLC 및 GC-ECD/NPD를 이용한 과일 중 61종 농약의 QuEChERS 전처리 다성분 분석법 개발" 한국농약과학회 16 (16): 242-256, 2012

      23 FAOSTAT, "FAOSTAT Crop production data. Food and Agril" Org of UN

      24 Benjamin M Nugent, "Expanding the structure-activity relationship of sulfoxaflor: the synthesis and biological activity of N-heterocyclic sulfoximines" Wiley 71 (71): 928-936, 2015

      25 Anna A. Bletsou, "Development of Specific LC-ESI-MS/MS Methods to Determine Bifenthrin, Lufenuron, and Iprodione Residue Levels in Green Beans, Peas, and Chili Peppers Under Egyptian Field Conditions" Springer Nature 6 (6): 1099-1112, 2013

      26 Jun Xu, "Determination of sulfoxaflor residues in vegetables, fruits and soil using ultra-performance liquid chromatography/tandem mass spectrometry" Royal Society of Chemistry (RSC) 4 (4): 4019-, 2012

      27 Chunyan Tian, "Determination of Sulfoxaflor in Animal Origin Foods Using Dispersive Solid-Phase Extraction and Multiplug Filtration Cleanup Method Based on Multiwalled Carbon Nanotubes by Ultraperformance Liquid Chromatography/Tandem Mass Spectrometry" American Chemical Society (ACS) 64 (64): 2641-2646, 2016

      28 Gerald B. Watson, "Characterization of a nicotinic acetylcholine receptor binding site for sulfoxaflor, a new sulfoximine insecticide for the control of sap-feeding insect pests" Elsevier BV 143 : 90-94, 2017

      29 Jeong-In Hwang, "Bioconcentration factor-based management of soil pesticide residues: Endosulfan uptake by carrot and potato plants" Elsevier BV 627 : 514-522, 2018

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