4 - 매개변수 대응상태원리로 전개된 BWRS 상태 방정식에 의한 극성 할로겐 탄화수소 화합물의 열역학 물성예측 = Thermophysical properties Prediction of Polar Halocarbons by the BWRS Equation of State Based on Four - Parameter Corresponding States Principle

다국어 초록 (Multilingual Abstract)

A four-parameter corresponding-states-principle framework has been employed to improve the thermophysical properties prediction of the polar halogenated hydrocarbons(halocarbons). The equation of state used here is the Benedict-Webb-Rubin-Starling(BWRS) equation. Reduced dipole moment is considered as the fourth parameter. And its constants have been generalized. The newly developed correlation with the generalized constants exhibits improved predictions of density, enthalpy and especially vapor pressure for halocarbons with high dipole moment without a sacrifice of predictability on low polar halocarbons.