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      전산유체역학을 이용한 Fischer-Tropsch 마이크로채널 반응기의 채널 구조 영향 분석 = Computational Fluid Dynamics Study of Channel Geometric Effect for Fischer-Tropsch Microchannel Reactor

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      https://www.riss.kr/link?id=A100267243

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      다국어 초록 (Multilingual Abstract)

      Driven by both environmental and economic reasons, the development of small to medium scale GTL(gasto- liquid) process for offshore applications and for utilizing other stranded or associated gas has recently been studied increasingly. Microchannel GT...

      Driven by both environmental and economic reasons, the development of small to medium scale GTL(gasto- liquid) process for offshore applications and for utilizing other stranded or associated gas has recently been studied increasingly. Microchannel GTL reactors have been prefrered over the conventional GTL reactors for such applications, due to its compactness, and additional advantages of small heat and mass transfer distance desired for high heat transfer performance and reactor conversion. In this work, multi-microchannel reactor was simulated by using commercial CFD code, ANSYS FLUENT, to study the geometric effect of the microchannels on the heat transfer phenomena. A heat generation curve was first calculated by modeling a Fischer-Tropsch reaction in a single-microchannel reactor model using Matlab-ASPEN integration platform. The calculated heat generation curve was implemented to the CFD model. Four design variables based on the microchannel geometry namely coolant channel width, coolant channel height, coolant channel to process channel distance, and coolant channel to coolant channel distance, were selected for calculating three dependent variables namely, heat flux, maximum temperature of coolant channel, and maximum temperature of process channel. The simulation results were visualized to understand the effects of the design variables on the dependent variables. Heat flux and maximum temperature of cooling channel and process channel were found to be increasing when coolant channel width and height were decreased. Coolant channel to process channel distance was found to have no effect on the heat transfer phenomena. Finally, total heat flux was found to be increasing and maximum coolant channel temperature to be decreasing when coolant channel to coolant channel distance was decreased. Using the qualitative trend revealed from the present study, an appropriate process channel and coolant channel geometry along with the distance between the adjacent channels can be recommended for a microchannel reactor that meet a desired reactor performance on heat transfer phenomena and hence reactor conversion of a Fischer-Tropsch microchannel reactor.

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      참고문헌 (Reference)

      1 양정일, "철 촉매를 이용한 Fischer-Tropsch 합성 반응과 수성 가스 전환 반응에 대한 반응 속도 연구" 한국화학공학회 50 (50): 358-364, 2012

      2 Menter, F. R., "Two-Equation Eddy-Viscosity Turbulence Models for Engineering Applications" 32 : 1598-, 1994

      3 Derevich, I. V., "Thermodynamics of Wax Formation in the Fischer-Tropsch Synthesis Products" 47 : 191-, 2013

      4 Oxford Catalysts Group PLC, "Technical experts’ report on the Velocys technology" Nexant, Inc 27-, 2008

      5 Derevich, I. V., "Simulation of Fluid Dynamics in a Microchannel Fischer-Tropsch Reactor" 46 (46): 8-19, 2012

      6 Lee, C.-J., "Optimal Gas-To-Liquid Product Selection from Natural Gas under Uncertain Price Scenarios" 48 : 794-, 2008

      7 TOYO EGINEERING, "Offshore GTL Process Development By Microchannel Reactor" 8 : 82-88, 2012

      8 Bajus, M., "Microchannel-Technologies" 54 : 294-300, 2012

      9 Jarosch, K. T., "Microchannel Reactors for Intensifying Gas-toliquid Technology" 914 : 258-272, 2005

      10 Derevich, I. V., "Liquid-Vpor Thermodynamic Equilibrium in Fischer-Tropsch Synthesis Products" 42 : 216-, 2008

      1 양정일, "철 촉매를 이용한 Fischer-Tropsch 합성 반응과 수성 가스 전환 반응에 대한 반응 속도 연구" 한국화학공학회 50 (50): 358-364, 2012

      2 Menter, F. R., "Two-Equation Eddy-Viscosity Turbulence Models for Engineering Applications" 32 : 1598-, 1994

      3 Derevich, I. V., "Thermodynamics of Wax Formation in the Fischer-Tropsch Synthesis Products" 47 : 191-, 2013

      4 Oxford Catalysts Group PLC, "Technical experts’ report on the Velocys technology" Nexant, Inc 27-, 2008

      5 Derevich, I. V., "Simulation of Fluid Dynamics in a Microchannel Fischer-Tropsch Reactor" 46 (46): 8-19, 2012

      6 Lee, C.-J., "Optimal Gas-To-Liquid Product Selection from Natural Gas under Uncertain Price Scenarios" 48 : 794-, 2008

      7 TOYO EGINEERING, "Offshore GTL Process Development By Microchannel Reactor" 8 : 82-88, 2012

      8 Bajus, M., "Microchannel-Technologies" 54 : 294-300, 2012

      9 Jarosch, K. T., "Microchannel Reactors for Intensifying Gas-toliquid Technology" 914 : 258-272, 2005

      10 Derevich, I. V., "Liquid-Vpor Thermodynamic Equilibrium in Fischer-Tropsch Synthesis Products" 42 : 216-, 2008

      11 Van der Laan, G. P., "Kinetics and Selectivity of the Fischer-Tropsch Synthesis: A Literature Review" 41 (41): 255-318, 1999

      12 H. Atashi, "Kinetic study of Fischer–Tropsch process on titania-supported cobalt–manganese catalyst" 한국공업화학회 16 (16): 952-961, 2010

      13 Yates, I. C., "Intrinsic Kinetics of the Fischer-Tropsch Synthesis on a Cobalt Catalyst" 5 (5): 168-173, 1991

      14 Jun, K.-W., "GTL: Manufacturing Technology of Natural Gas to Synthetic Crude Oil" 36 (36): 8-15, 2009

      15 Knochen, J., "Fischertropsch Synthesis in Milli-structured Fixed-bed Reactors: Experimental Study and Scale-up Considerations" 49 : 958-, 2010

      16 Kandlikar, S. G., "Extending the Heat Flux Limit with Enhanced Microchannels in Direct Single-phase Cooling of Computer Chips" 8-15, 2005

      17 Krishna, K. R., "Estimates of the Rate Coefficients for Chain Initiation, Propagation, and Termination during Fischer-Tropsch Synthesis over Ru/TiO2" 139 (139): 104-118, 1993

      18 Post, M., "Diffusion Limitations in Fischer-tropsch Catalysts" 35 : 1107-, 1989

      19 Farhad Fazlollahi, "Development of a kinetic model for Fischer–Tropsch synthesis over Co/Ni/Al2O3 catalyst" 한국공업화학회 18 (18): 1223-1232, 2012

      20 Kusakabe, K., "Development of a Microchannel Catalytic Reactor System" 18 : 271-, 2001

      21 Arzamendi, G., "Computational Fluid Dynamics Study of Heat Transfer in a Microchannel Reactor for Low-temperature Fischer-Tropsch Synthesis" 160 : 915-, 2010

      22 An, H., "Computational Fluid Dynamics (CFD) Analysis of Micro-reactor Performance: Effect of Various Configurations" 75 : 85-, 2012

      23 Guettel, R., "Comparison of Different Reactor Types for Lowtemperature Fischer-Tropsch Synthesis: A Simulation Study" 64 (64): 955-964, 2009

      24 Wang, Y., "Catalyst Structure and Method of Fischer-tropsch Synthesis"

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