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      Cr(VI)으로 오염된 부지의 안정화 기술에 의한 정화 타당성 연구 = Feasibility Study on Stabilization Technique of Cr(VI)-contaminated Site

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      https://www.riss.kr/link?id=A103630724

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      다국어 초록 (Multilingual Abstract)

      In this study, a remedial investigation using reductive stabilization was conducted to treat Cr(VI)-contaminated soil. The influences of various operational parameters, including reaction time and the mass of ferrous iron, were also evaluated. The stu...

      In this study, a remedial investigation using reductive stabilization was conducted to treat Cr(VI)-contaminated soil. The influences of various operational parameters, including reaction time and the mass of ferrous iron, were also evaluated. The study site was contaminated with a large amount of Cr(III) and Cr(VI), and the selected treatment method was to stabilize Cr(VI) with ferrous iron, which reduced Cr(VI) to Cr(III) and stabilized the chromium, although a greater mass of ferrous iron than the stoichiometric amount was required to stabilize the Cr(VI). However, some Cr(III) re-oxidized to Cr(VI) during the drying process, and addition of a strong reducing agent was required to maintain reducing conditions. With this reducing agent, the treated soil met the required regulatory standard, and the mass of Cr(III) re-oxidized to Cr(VI) was significantly reduced, compared to the use of only Fe(II) as a reducing agent.

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      참고문헌 (Reference)

      1 김록영, "토양오염공정시험기준 6가크롬 분석의 이해와 결과 해석" 한국토양비료학회 44 (44): 727-733, 2011

      2 이민희, "토양 세척법과 석회를 첨가한 토양 안정화 공법을 이용한 폐광산 주변 비소 오염 토양 및 하천 퇴적토 복원" 대한자원환경지질학회 37 (37): 121-131, 2004

      3 김록영, "우리나라 토양의 크롬 분포특성에 관한 고찰" 한국토양비료학회 43 (43): 296-303, 2010

      4 Lambeth, D.O., "The kinetics and mechanism of reduction of electron transfer proteins and other compounds of biological interest by dithionite" 248 : 6095-6103, 1973

      5 Morgan, B., "The effect of pH on the kinetics of spontaneous Fe(II) oxidation by O2 in aqueous solution--basic principles and a simple heuristic description" 68 : 2080-2084, 2007

      6 James, B. R., "The challenge of remediating chromiumcontaminated soil" 30 : A248-A251, 1996

      7 Fendorf, S. E., "Surface-Reactions of chromium in soils and waters" 67 : 55-71, 1995

      8 Kumpiene, J., "Stabilization of As, Cr, Cu, Pb and Zn in soil using amendments - A review" 28 : 215-225, 2008

      9 Kim, E. J., "Role of reducing agent in extraction of arsenic and heavy metals from soils by use of EDTA" 152 : 274-283, 2016

      10 Mulligan, C. N., "Remediation technologies for metal-contaminated soils and groundwater:an evaluation" 60 : 193-207, 2001

      1 김록영, "토양오염공정시험기준 6가크롬 분석의 이해와 결과 해석" 한국토양비료학회 44 (44): 727-733, 2011

      2 이민희, "토양 세척법과 석회를 첨가한 토양 안정화 공법을 이용한 폐광산 주변 비소 오염 토양 및 하천 퇴적토 복원" 대한자원환경지질학회 37 (37): 121-131, 2004

      3 김록영, "우리나라 토양의 크롬 분포특성에 관한 고찰" 한국토양비료학회 43 (43): 296-303, 2010

      4 Lambeth, D.O., "The kinetics and mechanism of reduction of electron transfer proteins and other compounds of biological interest by dithionite" 248 : 6095-6103, 1973

      5 Morgan, B., "The effect of pH on the kinetics of spontaneous Fe(II) oxidation by O2 in aqueous solution--basic principles and a simple heuristic description" 68 : 2080-2084, 2007

      6 James, B. R., "The challenge of remediating chromiumcontaminated soil" 30 : A248-A251, 1996

      7 Fendorf, S. E., "Surface-Reactions of chromium in soils and waters" 67 : 55-71, 1995

      8 Kumpiene, J., "Stabilization of As, Cr, Cu, Pb and Zn in soil using amendments - A review" 28 : 215-225, 2008

      9 Kim, E. J., "Role of reducing agent in extraction of arsenic and heavy metals from soils by use of EDTA" 152 : 274-283, 2016

      10 Mulligan, C. N., "Remediation technologies for metal-contaminated soils and groundwater:an evaluation" 60 : 193-207, 2001

      11 Mulligan, C.N., "Remediation of a heavy metal-contaminated soil by a rhamnolipid foam" 85 : 75-81, 2006

      12 Dossing, L. N., "Reduction of hexavalent chromium by ferrous iron: A process of chromium isotope fractionation and its relevance to natural environments" 285 : 157-166, 2011

      13 Kozuh, N., "Reduction and oxidation processes of chromium in soils" 34 : 112-119, 2000

      14 Sun, B., "Leaching of heavy metals from contaminated soils using EDTA" 113 : 111-120, 2001

      15 Fendorf, S. E., "Kinetics of chromate reduction by ferrous iron" 30 : 1614-1617, 1996

      16 Landrot, G., "Kinetics of Chromium(III) Oxidation by Manganese(IV) Oxides using Quick Scanning X-ray Absorption Fine Structure Spectroscopy (Q-XAFS)" 44 : 143-149, 2010

      17 Bacon, J.R., "Is there a future for sequential chemical extraction?" 133 : 25-46, 2008

      18 Kim, W. S., "In situ field scale electrokinetic remediation of multi-metals contaminated paddy soil: Influence of electrode configuration" 86 : 89-95, 2012

      19 Rauret, G., "Improvement of the BCR three step sequential extraction procedure prior to the certification of new sediment and soil reference materials" 1 : 57-61, 1999

      20 Wuana, R.A., "Heavy metals in contaminated soils: a review of sources, chemistry, risks and best available strategies for remediation" 2011 : 1-20, 2011

      21 Kachenko, A., "Heavy metals contamination in vegetables grown in urban and metal smelter contaminated sites in Australia" 169 : 101-123, 2006

      22 Abumaizar, R.J., "Heavy metal contaminants removal by soil washing" 70 : 71-86, 1999

      23 Jarup, L., "Hazards of heavy metal contamination" 68 : 167-182, 2003

      24 Hwang, B. R., "Extractive and oxidative removal of copper bound to humic acid in soil" 22 : 6077-6085, 2015

      25 Ryu, B. G., "Electrolyte conditioning for electrokinetic remediation of As, Cu, and Pb-contaminated soil" 79 : 170-176, 2011

      26 Fu, R. B., "Electrokinetic remediation of chromium (Cr)-contaminated soil with citric acid (CA) and polyaspartic acid (PASP) as electrolytes" 316 : 601-608, 2017

      27 Chen, M., "Comparison of three aqua regia digestion methods for twenty Florida soils" 65 : 491-499, 2001

      28 Butler, E. C., "Biological versus mineralogical chromium reduction: potential for reoxidation by manganese oxide" 17 : 1930-1940, 2015

      29 김주영, "6가크롬 오염토양 정화기술 현장적용성 연구" 한국지하수토양환경학회 15 (15): 57-65, 2010

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      2026 평가예정 재인증평가 신청대상 (재인증)
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      2002-01-01 평가 등재후보 1차 PASS (등재후보1차) KCI등재후보
      2000-07-01 평가 등재후보학술지 선정 (신규평가) KCI등재후보
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      학술지 인용정보
      기준연도 WOS-KCI 통합IF(2년) KCIF(2년) KCIF(3년)
      2016 0.3 0.3 0.35
      KCIF(4년) KCIF(5년) 중심성지수(3년) 즉시성지수
      0.35 0.36 0.568 0.05
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