<P>The dark side of the Mn: A manganese(III) complex bearing a 13-membered macrocyclic ligand (1, see picture) binds a peroxo ligand in a side-on η<SUP>2</SUP> fashion. The reactivity of 1 is influenced by the introduction of ani...
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https://www.riss.kr/link?id=A107594419
2009
-
SCIE,SCOPUS
학술저널
4150-4153(4쪽)
0
상세조회0
다운로드다국어 초록 (Multilingual Abstract)
<P>The dark side of the Mn: A manganese(III) complex bearing a 13-membered macrocyclic ligand (1, see picture) binds a peroxo ligand in a side-on η<SUP>2</SUP> fashion. The reactivity of 1 is influenced by the introduction of ani...
<P>The dark side of the Mn: A manganese(III) complex bearing a 13-membered macrocyclic ligand (1, see picture) binds a peroxo ligand in a side-on η<SUP>2</SUP> fashion. The reactivity of 1 is influenced by the introduction of anionic ligands trans to the peroxo group. Electronic and structural changes upon trans-ligand binding explain the increased nucleophilicity of the resulting complexes 1-X.
<img src='wiley_img/14337851-2009-48-23-ANIE200900118-content.gif' alt='wiley_img/14337851-2009-48-23-ANIE200900118-content'>
</P>
<B>Graphic Abstract</B>
<P>The dark side of the Mn: A manganese(III) complex bearing a 13-membered macrocyclic ligand (1, see picture) binds a peroxo ligand in a side-on η<SUP>2</SUP> fashion. The reactivity of 1 is influenced by the introduction of anionic ligands trans to the peroxo group. Electronic and structural changes upon trans-ligand binding explain the increased nucleophilicity of the resulting complexes 1-X.
<img src='wiley_img/14337851-2009-48-23-ANIE200900118-content.gif' alt='wiley_img/14337851-2009-48-23-ANIE200900118-content'>
</P>