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김종열,김정열,신창호,이근회,이동욱,제병권 한국연초학회 1999 한국연초학회지 Vol.21 No.2
This study was conducted to evaluate the effect of cigarette papers, flax and wood, on the delivery of mainstream smoke. The main components of cigarette papers were cellulose, hemicellulose, lignin, and pectin. Lignin contents, known as precursor of smoke's phenolic compounds, of the flax and wood cigarette papers were 5.8% and 10.6%, respectively. The pyrolysis products of cigarette papers were similar by the profile of total ion chromatogram. But, the area % of some components, such as 1,3-cyclopentanedione, 3,5- dimethyl cyclopentane-1,2-dione, 2-hydroxy-3-methyl-2-cyclopentenone, dihydro-2(3H)-furanone, 3-methyl-2(5H)-fruanone, and 5-methyl-2-furaldehyde delivered through pyrolysis of the flax cigarette paper were higher than that of wood cigarette paper. Otherwise, the area % of some components, such as 2-methyl-cyclopentene-l-one), 2,3-butanedione, 2-cyclopentene-l-one, and 5-hydroxy-2-methyl-furaldehyde, 2-furaldehyde delivered through pyrolvsis of the wood cigarette paper were higher than that of flax cigarette paper. To identify the difference between two cigarette papers, we used the cigarette column filled with the cut cigarette paper instead of the cut tobacco leaf. The amounts of semi-volatile fraction delivered from flax cigarette paper was more than that of wood cigarette paper. But, by using the cut tobacco, there was no big difference of delivery amount between flax and wood cigarette papers. Also, aroma of TPM by collecting from brening cut tobacco wrapped in flax and wood papers showed a different pattern by the electonic nose system. Although the difference between two cigarette papers by using the cut tobacco was smaller than that of cut cigarette paper, this result indicated that the fax and wood had the different effects on the delivery of smoke components as shown in the sensory test results.
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Lyocell 섬유를 함유한 종이의 제조 및 적용에 관한 연구( I )
김종열,류운형,유성종,김정열,신창호,김영호 한국연초학회 2000 한국연초학회지 Vol.22 No.1
In order to investigate the applicability of lyocell fiber to filter paper, papper sheets were manufactured with the addition of lyocell fibers in various length(1.5 denier: 2, 3, 4mm) and content(10, 30, 50%) and their physical characters, such as fibrilation rate, adsorption efficiency of methylene blue(MB), paper formation, and crimping ability, etc, were tested. The level of main fibrilation from lyocell fiber was higher in wet beating process than that in free beating because of the higher strength of lyocell fiber compared with wood fiber. Fibrilation could be observed at the degree of beating over 30$^{\circ}$ SR in wet beating with Valley beater. The air permeability and tear factor of the paper increased and the paper formation index decreased according to the increase of fiber length. The weak binding force of lyocell fiber in spite of its higher fiber strength, might be a limitng factor in addition of lyocell fiber to the natural wood pulp in manufacturing the paper having the needed physical properties. High contents of wood pulp decreased air permeability, the breaking length, tear factor, the bursting strength, and paper formation index in paper sheets. As the contents of lyocell increased from 10% to 100%, the adsorption efficiency of MB was elevated to 1.7-7.9 times compared with that in 100% wood pulp. But the length of lyocell fiber did not affect the MB adsorption.
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Triacetin 함량에 따른 담배필터의 이화학적 특성에 관한 연구
김종열,신창호,김정열,김영호,이근회 한국연초학회 1997 한국연초학회지 Vol.19 No.2
This study was carried out to investigate the influence of triacetin(TA) on some phisico-chemical properties of cigarette filter rods. To find the effect of TA on physical properties, we made six kinds of filters varying the TA levels(0%, 2%, 4%, 6%, 8%, 10%) and measured the hardness, resilience and roundness. The hardness of filter rods was increased from 83.2% to 94.6% with increasing the TA level hut the roundness was not affected by TA levels. After manufacturing the cigarette with the filters, we have analysed the delivery amount of phenol and TA with the content of TA. The amount of phenol was decreased from 20.6$\mu\textrm{g}$/cig. to 12.0 $\mu\textrm{g}$/cig. with increasing the TA level of the filters. The decreasing of phenol amount was thought to be caused by solution effect. Also the TA delivery of TPM was increased from 0% to 5% of TPM with increasing the amount of TA. We have found the interesting phenomena that ventilation rate was also decreasing up to 6oye with increasing TA. It seemed to be due to the encapsulated pressure drop and the reduction of the plugwrap porosity which also caused by the smear with TA on the surface of plugwrap. From this results, we could find that not only the hardness, resilience and ventilation rate but also the contents of phenol and TA in cigarette smoke was affected by the TA levels on the cigarette filter rods.
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김종열,김수호,신창호,박진원,임성진,김정렬,이문수,Kim Jong-Yeol,Kim Soo-Ho,Shin Chang-Ho,Park Jin-Won,Lim Sung-Jin,Kim Chung-Ryul,Rhee Moon-Soo 한국연초학회 2006 한국연초학회지 Vol.28 No.1
The objective of the present study is to induct the regression equation for the hardness prediction of cellulose acetate filter which was manufactured by the domestic cellulose acetate tow manufacturer. As a result of our study, the hardness of filter was increased with increasing the plasticizer content and packing density as major factors affecting to the filter hardness. As a result which was obtained by the three dimensional response surface methodology in STATISTIC A program, the hardness prediction value well fitted with experiment result on the high plasticizer content. To make up for the this equation, the new modified fraction of solid factors which was contained the mono denier factor was introduced to the hardness prediction equation, and this third regression equation which was sufficient for the wide plasticizer content, was obtained by the three dimensional response surface methodology in STATISTICA. This results indicated that the third regression equation which was obtained this study was applicable for the hardness prediction of cellulose acetate filter which was manufactured by the domestic cellulose acetate tow manufacturer.
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광섬유 브래그 격자 센서를 이용한 국내외 상용 단일모드 광섬유의 감마선 영향 연구
김종열,이남호,Kim, Jong-Yeol,Lee, Nam-Ho 한국정보통신학회 2012 한국정보통신학회논문지 Vol.16 No.10
본 논문에서는 Ge가 함유된 일반 단일모드 광섬유의 감마선 유입손실을 측정하였다. 방사선 선원은 $Co^{60}$ 감마선 선원을 이용하였으며, 총 4시간동안 0.5 kGy/hr, 2 kGy/hr, 8 kGy/hr의 선량률로 조사하였다. 그 결과 감마선 조사에 의한 단일모드 광섬유의 전송손실이 뚜렷하게 나타났으며, 동일 누적선량에서 선량률이 클수록 전송손실이 증가하는 선량률 효과가 나타났다. 또한 감마선 조사 종료 후 광섬유의 전송손실이 클수록 유입손실의 회복률이 증가하는 어닐링 특성을 보였다. 본 실험결과는 향후 광섬유의 내방사화 연구의 기초자료로 활용할 것이다.
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