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Kwang Soon Choi,Gi Yong Kim,Jung-Weon Choi,Jung Bo Yoo,Tae-Hong Park 한국방사성폐기물학회 2022 한국방사성폐기물학회 학술논문요약집 Vol.20 No.2
We established pretreatment method of solidified cement ion-exchange resin samples generated before 2003 in nuclear power plants for measurement of non-volatile radionuclide activity. A microwave digestion system (MDS) with mixed acid (HCl-HNO3-HF-H2O2) was used to dissolve cement and to desorb non-volatile elements such as Ce, Co, Cs, Fe, Nb, Ni, Re, Sr and U from mixed ion-exchange resin. The content of Ce, Co, Fe, Nb, Ni, Re, Sr, U and Cs after pretreatment of cement plus mixed ion-exchange resin was measured by ICP-AES and ICP-MS, respectively. As iron and strontium are also present in cement, their content after dissolving a certain amount of cement was measured by ICP-AES. All elements except Nb were quantitatively recovered. Especially since the Nb recovery was low at 72.0±2.5%, the MDS following addition of the mixed acid to the resin was operated once more for desorbing Nb from it. Finally the recovery of Nb was over 95%. This sample pretreatment method will be applied to solidified cement ion-exchange resin samples generated in nuclear power plants for assessment of radionuclide inventory.
( Ji Young Jung ),( Myung Suk Choi ),( Ji Su Kim ),( Mi Jin Jeong ),( Young Wun Kim ),( Byeong Tae Woon ),( Jin Ki Yeo ),( Han Na Sin ),( Young Bon Goo ),( Keun Ok Ryu ),( Chandrakant S. Karigar ),( J 한국임학회 2010 한국산림과학회지 Vol.99 No.5
Enzymatic hydrolysate from non pre-treated biomass of yellow poplar (Liriodendron tulipifera) was prepared and used as resource for bioethanol production. Fresh branch (1 year old) of yellow poplar biomass was found to be a good resource for achieving high saccharification yields and bioethanol production. Chemical composition of yellow poplar varied significantly depending upon age of tree. Cellulose content in fresh branch and log (12 years old) of yellow poplar was 44.7 and 46.7% respectively. Enzymatic hydrolysis of raw biomass was carried out with commercial enzymes. Fresh branch of yellow poplar hydrolyzed more easily than log of yellow poplar tree. After 72 h of enzyme treatment the glucose concentration from Fresh branch of yellow poplar was 1.46 g/L and for the same treatment period log of yellow poplar produced 1.23 g/L of glucose. Saccharomyces cerevisiae KCTC 7296 fermented the enzyme hydrolysate to ethanol, however ethanol production was similar (~1.4 g/L) from both fresh branch and log yellow poplar hydrolysates after 96 h.
Jung, Ji-Young,Choi, Myung-Suk,Kim, Ji-Su,Jeong, Mi-Jin,Kim, Young-Wun,Woon, Byeng-Tae,Yeo, Jin-Ki,Shin, Han-Na,Goo, Young-Bon,Ryu, Keun-Ok,Karigar, Chandrakant S.,Yang, Jae-Kyung Korean Society of Forest Science 2010 한국산림과학회지 Vol.99 No.5
Enzymatic hydrolysate from non pre-treated biomass of yellow poplar (Liriodendron tulipifera) was prepared and used as resource for bioethanol production. Fresh branch (1 year old) of yellow poplar biomass was found to be a good resource for achieving high saccharification yields and bioethanol production. Chemical composition of yellow poplar varied significantly depending upon age of tree. Cellulose content in fresh branch and log (12 years old) of yellow poplar was 44.7 and 46.7% respectively. Enzymatic hydrolysis of raw biomass was carried out with commercial enzymes. Fresh branch of yellow poplar hydrolyzed more easily than log of yellow poplar tree. After 72 h of enzyme treatment the glucose concentration from Fresh branch of yellow poplar was 1.46 g/L and for the same treatment period log of yellow poplar produced 1.23 g/L of glucose. Saccharomyces cerevisiae KCTC 7296 fermented the enzyme hydrolysate to ethanol, however ethanol production was similar (~1.4 g/L) from both fresh branch and log yellow poplar hydrolysates after 96 h.
표면 개질된 샤프심 전극의 전기화학적 특성 고찰 및 비효소적 글루코스 센서 활용
송민정 한국화학공학회 2024 Korean Chemical Engineering Research(HWAHAK KONGHA Vol.62 No.2
의료용 센서들은 대부분 일회용 제품으로, 검사·진단 비용을 줄이기 위해서는 저가의 전극 소재 개발이 무엇보다 중요하다. 본 연구에서는 일회용 전기화학센서의 전극 소재로 pencil graphite를 도입하여 전처리 효과와 전도성 고분자 폴리아닐린(polyaniline; PANI) 및 금속 산화물 CuO NPs를 이용한 표면 개질(modification)을 통한 전기화학적 특성을 조사하고, 이를 글루코스 검출용 비효소 전기화학센서에 적용하였다. Pencil graphite electrode (PGE)의 표면 활성화를 위한 전처리는 화학적과 전기화학적으로 각각 진행되었으며, 전처리된 샘플들은 시간대전류법(CA)과 순환전압 전류법(CV), 전기화학 임피던스(EIS) 분석법을 이용한 전기화학적 특성 조사를 통해 최종적으로 전기화학적 전처리 방법을 채택하여 CuO NPs/PANI/E-PGE를 제작하였다. 이를 적용한 비효소적 글루코스 검출용 전기화학 센서는 0.282 ~2.112mM과 3.75423~50 mM의 선형 구간에서 각각 239.18 mA/mM×cm2과 36.99 mA/mM×cm2 정도의 감도(sensitivity)와 17.6μM의 검출 한계(detection limit), 글루코스에 대한 좋은 선택도(selectivity)를 보였다. 본 연구의 결과를 토대로 PGEs를 활용한 다양한 일회용 센서 응용과 저가의 고성능 전극 소재 개발 가능성을 확인하고, 더 많은 분야에 활용할 수 있을 것으로 기대된다. Most medical sensors are disposable products. In order to reduce inspection and diagnosis costs, it is more important to develop the inexpensive electrode materials. We fabricated the CuO NPs/PANI/E-PGE as an electrode material for disposable electrochemical sensors and applied it to a non-enzymatic glucose sensor. For surface activation of PGE, pretreatment was performed using chemical and electrochemical methods, respectively. Electrochemical properties according to the pretreatment method were analyzed through chronoamperometry (CA),cyclic voltammetry (CV) and electrochemical impedance (EIS). From these analytical results, the electrochemically pretreated PGE (E-PGE) was finally adopted. The non-enzymatic glucose sensor based on CuO NPs/PANI/E-PGE shows sensitivity of 239.18 mA/mM×cm2 (in a linear range of 0.282~2.112 mM) and 36.99 mA/mM×cm2 (3.75423~50mM), detection limit of 17.6 μM and good selectivity. Based on the results of this study, it was confirmed that the modified PGE is a high-performance electrode material. Therefore, these electrodes can be applied to a variety of disposable sensors.