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황영기,정은혁 경남대학교 신소재연구소 1994 論文集 Vol.4 No.-
직경이 388㎛와 543㎛인 구형의 구리입자를 충전시킨 유동층 전극반응기에서 1,000ppm의 황산동이 용해되어 있는 0.5M H₂SO₄수용액으로부터 구리이온을 음극전착하는 환원반응을 수행하였다. 전해질 유속을 2-10㎝/s의 범위로 조절하면서, 직경이 0.5㎝인 8개의 점전극이 설치된 전류공급원의 위치에 따른 국부물질전달계수와 전류공급원전체에 대한 총관물질전달계수를 구하였다. 유동층 전극반응기내에서의 물질전달계수는 전해질의 유속이 감소함에 따라서 전해질 축방향으로 내려옴에 따라서 증가하였으며, 같은 유속에서는 입자경이 큰 경우에서 입자경이 작은 경우보다 크게 나타남을 알 수 있었다. 유동층 전극반응기내에서의 물질전달 상관관계는 다음과 같은 무차원식으로 나타낼 수 있었다. In a fluidised bed electrode reactor packed with conductive copper particles of 388μm or 543μm diameter, reduction of copper ion has been performed from the electrolyte of 1,000ppm copper sulfate dissoluted in the 0.5M sulfuric acid. Varing the flow velocity of the electrolyte from 2cm/s to l0cm/s, over-all mass transfer coefficients and local mass transfer coefficients have been measured at the current feeder and at eight point-electrodes located on the current feeder, respectively. The mass transfer coefficients increased with decreasing both of the flow velocity of the electrolyte and the height of the point-electrode along the axial flow direction. They also increased with increasing the diameter of particle under the condition of constant velocity of the electrolyte. Mass transfer coefficients were correlated with Sherwood number, Reynolds number, and Schmidt number as follows. Sh = 0.03 Sc^{1/3}·{Re/(l-ε)}^{0.47} for over-all mass transfer Sh, = 86.33 Sc^{1/3}·{(Re/(l-ε)}·(d_{eq}/x)}^{0.16} for local mass transfer
황영기,정은혁 한국환경과학회 1997 한국환경과학회지 Vol.6 No.1
Varing the flow velocity of solution and particle diameter, the mass transfer coefficient of the local electrode on current feeder has been measured in an empty flow reactor, an inert fluidized bed electrode reactor, and an active fluidized bed electrode reactor. It had its maximium value when the bed porosity was 0.6 to 0.65 and decreased with increasing the height of local electrode. The mass transfer coefficient was found to be high especially when bigger particle was fluidized. Electrochemical deposition of copper dissolved in the synthesized wastewater has been performed in the active fluidized bed electrode reactor. The deduction rate was higher than 90% and the residual concentration of copper decreased to less than 5ppm.