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Quasi-2D Ruddlesden-Popper 할라이드 페로브스카이트의 형성 메커니즘의 이해
박예랑,황인찬 한국세라믹학회 2022 세라미스트 Vol.25 No.3
Two dimensional (2D) or quasi-2D halide perovskites have attracted intense interest in recent years for the replacement of three dimensional(3D) perovskites, owing to their stability and structural/optoelectronic tunability. However, the control of their composition and orientation is challenging when solution processed for thin films, because of the similarity in formation energy for different layer numbers. In this review, we discuss the factors affecting formation of 2D and quasi 2D perovskites, especially Ruddlesden-Popper perovskites, in solution-processed thin films. All the factors are associated with nucleation and growth kinetics, which affect their phase distribution and orientation. Furthermore, the performances of the photovoltaics and light-emitting diodes based on the controlled quasi-2D perovskites are briefly discussed.
Grain Growth Behavior of (K0.5Na0.5)NbO3 Ceramics Doped with Alkaline Earth Metal Ions
유일열,최성희,조경훈 한국재료학회 2023 한국재료학회지 Vol.33 No.4
The volatilization of alkali ions in (K,Na)NbO3 (KNN) ceramics was inhibited by doping them with alkaline earth metal ions. In addition, the grain growth behavior changed significantly as the sintering duration (ts) increased. At 1,100 °C, the volatilization of alkali ions in KNN ceramics was more suppressed when doped with alkaline earth metal ions with smaller ionic size. A Ca2+-doped KNN specimen with the least alkali ion volatilization exhibited a microstructure in which grain growth was completely suppressed, even under long-term sintering for ts = 30 h. The grain growth in Sr2+-doped and Ba2+-doped KNN specimens was suppressed until ts = 10 h. However, at ts = 30 h, a heterogeneous microstructure with abnormal grains and small-sized matrix grains was observed. The size and number of abnormal grains and size distribution of matrix grains were considerably different between the Sr2+-doped and Ba2+-doped specimens. This microstructural diversity in KNN ceramics could be explained in terms of the crystal growth driving force required for two-dimensional nucleation, which was directly related to the number of vacancies in the material.