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        Nanosecond laser induced energetic ion formation from a nanoparticle: The origin of ion detection loss in a single particle mass spectrometry

        Oh, Yongsuk,Zahaf, Riyan,Zachariah, Michael R.,Lee, Donggeun Institute of Pure and Applied Physics 2014 Japanese Journal of Applied Physics Vol. No.

        <P>Here we study the interaction of a nanosecond laser pulse with a nanoparticle to explore the mechanism of energetic ion formation and in particular the particle size dependence. Multiphoton ionization and the subsequent electron impact ionization accompanied by inverse Bremsstrahlung process are determined appropriate for generation of multiple charged ions. The Coulomb expansion of a positive ion cloud is then calculated with molecular dynamics simulations, resulting in temporal evolution of ions, a radial distribution of kinetic energy of ions, and size-dependency of the ion kinetic energy. A mass spectrum peak of ion simulated by the present model is found comparable to the experimental data. Alternatively, a direct measurement of kinetic energy is also explained by the model. (C) 2014 The Japan Society of Applied Physics</P>

      • Statistical analysis and modelization of tool life and vibration in dry face milling of AISI 52100 STEEL in annealed and hardened conditions

        Benghersallah, Mohieddine,Medjber, Ali,Zahaf, Mohamed Zakaria,Tibakh, Idriss,Amirat, Abdelaziz Techno-Press 2020 Advances in materials research Vol.9 No.3

        The objective of the present work is to investigate the effect of cutting parameters (Vc, fz and ap) on tool life and the level of vibrations velocity in the machined part during face milling operation of hardened AISI 52100 steel. Dry-face milling has been achieved in the annealed (28 HRc) and quenched (55 HRc) conditions using multi-layer coating micro-grain carbide inserts. Statistical analysis based on the Response surface methodology (RSM) and ANOVA analysis have been conducted through a plan of experiments methodology using a reduced Taguchi table (L9) in order to obtain engineering models for tool life and vibration velocity in the workpiece for both heat treatment conditions. The results show that the cutting speed has a dominant influence on tool life for both soft and hard part. Cutting speed and feed per tooth is the most significant parameters for vibration levels. Comparing the experimental values with those predicted by the developed engineering models of tool life and levels of vibrations velocity, a good correlation has been obtained (between 97% and 99%) in annealed and hard conditions.

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        Numerical simulations of supersonic gas atomization of liquid metal droplets

        Firmansyah, Dudi Adi,Kaiser, Rashed,Zahaf, Riyan,Coker, Zach,Choi, Tae-Youl,Lee, Donggeun Institute of Pure and Applied Physics 2014 Japanese Journal of Applied Physics Vol. No.

        <P>Computational fluid dynamics simulations incorporating supersonic turbulent gas flow models and a droplet breakup model are performed to study supersonic gas atomization for producing micron-sized metal powder particles. Generally such atomization occurs in two stages: a primary breakup and a secondary breakup. Since the final droplet size is primarily determined by the secondary breakup, parent droplets of certain sizes (1 to 5 mm) typically resulting from the primary breakup are released at the corner of the nozzle and undergo the secondary breakup. A comparison of flow patterns with and without the introduction of a liquid melt clearly indicates that the mass loading effect is quite significant as a result of the gas-droplet interactions. The flow pattern change reasonably explains why the final droplets have a bimodal mass size distribution. The transient size changes of the droplets are well described by the behavior of the Weber number. The present results based on the 1 mm parent droplets best fit previous experimental results. Moreover, the effects of inlet gas pressure and temperature are investigated in an attempt to further reduce droplet size. (C) 2014 The Japan Society of Applied Physics</P>

      • Microstructural Behavior of the Alumina Shell and Aluminum Core Before and After Melting of Aluminum Nanoparticles

        Firmansyah, Dudi Adi,Sullivan, Kyle,Lee, Kwang-Sung,Kim, Yong Ho,Zahaf, Riyan,Zachariah, Michael R.,Lee, Donggeun American Chemical Society 2012 JOURNAL OF PHYSICAL CHEMISTRY C - Vol.116 No.1

        <P>The oxidation mechanism of nanoaluminum particles, nominally employed as fuel component, is still an unsettled problem, because of the complex nature of thermomechanical properties of the oxide shell surrounding the elemental core. Although mechanical breakage of the alumina shell upon or after melting of aluminum core has been thought to play a key role in the combustion of aluminum nanoparticles, there has been little direct evidence. In this study, the microstructural behaviors of Al core and alumina shell lattices were investigated with increasing temperatures. Three in situ techniques, high-temperature X-ray diffraction analysis, hot-stage transmission electron microscopy, and high-resolution transmission electron microscopy for heat-treated samples, were employed to probe the thermal behaviors of aluminum and alumina lattices before and after melting of the aluminum core. High-temperature X-ray diffraction analysis revealed that nano aluminum lattice was initially expanded under tension at room temperature, and then when heated passed through a zero-strain state at ∼300 °C. Upon further heating above the bulk melting temperature of aluminum, the aluminum lattice expanded under almost no constraint. This interesting observation, which is contrary to almost all of the previous results and models, was ascribed to the inhomogeneous (localized) crystalline phase transformation of amorphous alumina. High-resolution transmission electron microscopy and in situ hot-stage transmission electron microscopy evidenced localized phase transformation accompanied by a significant shell thickening, presumably resulting from diffusion processes of Al cations and O anions, which is to absorb the pressure built in aluminum core, by creating a more ductile shell.</P><P><B>Graphic Abstract</B> <IMG SRC='http://pubs.acs.org/appl/literatum/publisher/achs/journals/content/jpccck/2012/jpccck.2012.116.issue-1/jp2095483/production/images/medium/jp-2011-095483_0009.gif'></P>

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