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        Rapid and effective removal of sodium lignosulfonate from aqueous solutions by in-situ formed magnesium hydroxide

        Tao Wu,Yujiang Li,Lanlan Ye,Feng Li 한국화학공학회 2016 Korean Journal of Chemical Engineering Vol.33 No.12

        We investigated the efficiency of in-situ formed magnesium hydroxide (Mg(OH)2) for the removal of sodium lignosulfonate (SLSN) from aqueous solution. Adsorption experiments considered the effects of various conditions such as pH, MgCl2 concentration, contact time, and temperature on SLSN removal efficiency. It was found that approximately 93%-99% SLSN was removed by in-situ formed Mg(OH)2. The adsorption was rapid, and the contact time required to reach complete adsorption equilibrium was less than 2min. Moreover, that the Mg(OH)2 lost about 0.5-3.0% adsorption capacity for SLSN when NO3 −, HCO3 −, H2PO4 − and SO4 2− anions were simultaneously present with SLSN. The experimental data suggested that there was little competitive adsorption of SLSN with other coexisting anions on Mg(OH)2. The co-precipitation/adsorption process was exothermic and physical, involving weak interactions such as electrostatic attraction, hydrogen bonding, adhesive forces, and van der Waals forces between SLSN molecules and the binding sites on Mg(OH)2.

      • KCI등재

        Enhanced adsorption capacity of dyes by surfactant-modified layered double hydroxides from aqueous solution

        Bei Zhang,Zhihao Dong,Dejun Sun,Tao Wu,Yujiang Li 한국공업화학회 2017 Journal of Industrial and Engineering Chemistry Vol.49 No.-

        The utilization of organo-modified layered double hydroxides with anionic surfactants (organo-LDHs) asadsorbents were successfully carried out to remove various synthetic dyes from aqueous solution. Intercalation of anionic surfactants changed the surface properties of MgAl-LDH from hydrophilic tohydrophobic, and a charge inversion occurred with increasing the length of surfactant chains. Suchchanges in the surface properties of the organo-LDHs were important. Experimental data shown that theSNS-modified MgAl-LDH could be used as a broad-spectrum adsorbent to effectively remove anionic,non-ionic, and cationic dyes from aqueous solution.

      • KCI등재

        Superwetting TiO2-decorated single-walled carbon nanotube composite membrane for highly efficient oil-in-water emulsion separation

        Yahong Sun,Ruiguang Zhao,Quanyong Wang,Yuanyuan Zheng,Gongrang Li,Dejun Sun,Tao Wu,Yujiang Li 한국화학공학회 2020 Korean Journal of Chemical Engineering Vol.37 No.11

        With the advantages of one-dimensional hollow structure, high porosity and prominent mechanical strength, single-walled carbon nanotubes (SWCNTs) have been extensively utilized to improve conventional filtration membranes for oil/water separation. Their intrinsic hydrophobicity, however, adversely affects the anti-fouling performance of the SWCNT membrane. Herein, a super-hydrophilic and underwater super-oleophobic hierarchical modified membrane with enhanced permeability and anti-fouling property was fabricated using the vacuum-assisted filtration technique by synergistically assembling SWCNTs and titanium dioxide (TiO2) nanoparticles on a cellulose acetate membrane. Highly dispersed SWCNTs were obtained by carboxylating treatment of agglomerate SWCNTs. The controlled stacking of SWCNTs fibers and a controllable amount of TiO2 rendered a modified membrane with high porosity and hierarchical structure, leading to an ultrahigh water flux up to 4,777.07 L·m2·h1, and excellent separation performance with efficiency greater than 99.47%. Most importantly, the membrane exhibited excellent anti-fouling ability during ten cycles with the aid of the super-wetting property of TiO2 nanoparticles. The results indicated that coating TiO2 nanoparticles on SWCNTs modified the surface topography of the obtained SWCNT/TiO2 membrane, which improved hydrophilicity, permeability and anti-fouling property, manifesting attractive potential applications in oil/water separation.

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