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Yuanpeng Fu,Yaqun He,Hangchao Chen,Cuiling Ye,Qichang Lu,Rongnian Li,Weining Xie,Jie Wang 한국공업화학회 2019 Journal of Industrial and Engineering Chemistry Vol.79 No.-
The present work focuses on simultaneous recycling of Li and Co from crushed products of mixedelectrode materials using mixed organic acids, in which benzenesulfonic acid and formic acid werecooperatively used as the leaching reagents. Results show that the optimal leaching efficiency of 97% Coand 99% Li were obtained under the conditions of 1.3 mol/L benzenesulfonic acid, 1.5 mol/L formic acid, asolid to liquid (S/L) ratio of 30 g/L, and 40 min reaction time at 50 C. Meanwhile, the leaching of Li and Cofits well to logarithmic rate model with apparent activation energy of 32.7 and 47.0 kJ/mol in this givenleaching system, respectively. Besides, cobalt was directly recovered from the leach liquor as pure cobaltbenzene sulfonic with the recovery efficiency of 99%, and lithium can be entirely precipitated by addingphosphoric acid. Further, the reaction mechanism involves the leaching-hydrating-complexing model ofLiCoO2 particles was proposed based on the dissolution behavior of metals and then verified bymorphological and phase characterization (i.e. FT-IR, XRD and SEM-EDS) of the recycling product. Thewhole process is found to be effective and sustainable for recovery of Li, Co and graphite from mixedindustrial crushing product of spent LIBs.
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Improving the Microbial Production of Amino Acids: From Conventional Approaches to Recent Trends
Guoqing Zhang,Xueni Ren,Xiuhong Liang,Yaqun Wang,Dexin Feng,Yujun Zhang,Mo Xian,Huibin Zou 한국생물공학회 2021 Biotechnology and Bioprocess Engineering Vol.26 No.5
Variable industrial strains have been applied in the fermentation of bulk amino acids. Strain discovery and evolution, process optimization are traditional approaches to improve the yield and efficiency of the bio-production process, hence to compete with chemical or enzymatic process in amino acids production. With the fast development of bioengineering and synthetic biology, the strains can be rationally engineered to achieve better performance and gain the capacity in the fermentation of broader range of amino acids, especially for value-added amino acids. This proposed review aims to summarize traditional and recent strains in the microbial production of amino acids, characterize their metabolic pathways and present potential objectives for rational evolution. In addition, this proposed review prospect the recent opportunities and challenges in the microbial production of value-added amino acids (rare amino acids, non-canonical amino acids, and unnatural amino acids).
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