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        Coagulation performance of a novel poly-ferric-acetate (PFC) coagulant in phosphate-kaolin synthetic water treatment

        Yanxin Wei,Jinpeng Lu,Xiongzi Dong,Jianwen Hao,Chengli Yao 한국화학공학회 2017 Korean Journal of Chemical Engineering Vol.34 No.10

        The process of coagulation-flocculation is increasingly applied in wastewater treatment. And the polymerized inorganic coagulants are widely used among these coagulation-flocculation processes. However, conventional coagulants using sulfates or chlorides as counter anion may give rise to corrosion. The purpose of this study was to synthesize PFC coagulants in which acetate is used as counter anion. The influences on the preparation of PFC were optimized. The synthesis was done at the optimum conditions, such as temperature of 60 oC, the Fe/CH3COOH molar ratio of 1 : 4.0 and reaction time of 6 h, respectively. The prepared PFC coagulants were characterized by Fourier transform infrared (FTIR) spectrophotometry and scanning electron microscopy (SEM). PFC was found to mainly form complexation polymeric species and present more cluster and lamellar structure. A series of jar tests were carried out to study the coagulation performance of PFC and PFS in phosphate-kaolin synthetic water treatment. Results showed that the coagulation performance of PFC was more efficient than PFS’s in terms of the phosphorus removal efficiency and the residual turbidity. Due to using acetate as counter anion to iron, PFC is less harmful to the processes of water treatment and equipment than that of the conventional coagulants applied chlorides or sulfates. Therefore, PFC is a promising coagulant in the process of corrosion sensitive applications and the process of wastewater containing phosphorus treatment.

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        Comparison of polysilicic acid (PSiA) and magnesium sulfate modified polysilicic acid (PMSiS) for effective removal of Congo red from simulated wastewater

        Yanxin Wei,Aimin Ding,Fabao Luo,Na Li,Chengli Yao 한국화학공학회 2020 Korean Journal of Chemical Engineering Vol.37 No.6

        Polymagnesium silicate sulfate (PMSiS) was prepared by using magnesium sulfate modified polysilicic acid (PSiA). The PMSiS’s functional group and morphology were analyzed by FTIR and SEM, respectively. The coagulation performance of PMSiS and PSiA was studied and compared in terms of the Congo red (CR) dye removal efficiency. After modification, PMSiS was a complexation polymeric species with the compact rod-like structure. Compared with PSiA, PMSiS was more efficient and stable. In the process of treating simulated wastewater containing CR dye, the dye removal efficiency of PMSiS could achieve above 80% at the lower coagulant dosage of 0.4 g/L, while the dye removal efficiency of PSiA could only reach about 70% at the higher coagulant dosage of 1.2 g/L. Moreover, PMSiS had wider applicable range of dosage and temperature than PSiA at optimal conditions of pH 12 and once addition of feeding mode. Therefore, PMSiS will be a promising coagulant in the process of treating practical wastewater containing dyes.

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