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Y.T. Ravikiran,S. Kotresh,S.C. Vijayakumari,S. Thomas 한국물리학회 2014 Current Applied Physics Vol.14 No.7
In the present research, liquid petroleum gas (LPG) sensing properties of polyaniline-carboxymethyl cellulose (PANI-CMC) composite have been investigated. For the purpose of investigation, PANI and PANI-CMC composite are synthesized at room temperature by chemical polymerization of aniline without/with CMC. The prepared materials are characterized by X-ray diffraction (XRD) and Scanning electron microscopy (SEM) techniques. Shift in d-space of PANI in the composite as confirmed by its XRD analysis suggests ordered PANI chain arrangement in the composite. Surface morphology and size of the particles are studied by SEM technique. Nature of the material and mechanism of conduction of both PANI and PANI-CMC composite are investigated by studying complex plane impedance plot in the frequency range of 102e106 Hz. Based on structural characterizations and impedance studies, sensitivity of PANI and PANI-CMC composite to LPG at room temperature are tested and compared. Further, to examine the efficiency of the composite as a sensor, its stability, recovery and response time have also been studied with a special focus on its ability to work at room temperature.
Babu Reddy, L.P.,Megha, R.,Chethan, B.,Raj Prakash, H.G.,Ravikiran, Y.T.,Ramana, C.H.V.V.,Kim, D. ELSEVIER 2018 Inorganic Chemistry Communications Vol.98 No.-
<P><B>Abstract</B></P> <P>In the present work, we prepared magnesium ferrite/molybdenum trioxide (MFMO) nanocomposite using mechano chemical mixing method for humidity sensor at room temperature. Enhancement in active sites for water adsorption in the composite due to the presence of MoO<SUB>3</SUB> confirmed from X-ray diffraction (XRD) studies. Change in grain size distribution and increase in intergranular pores in the composite favouring water adsorption confirmed from its scanning electron microscopy (SEM) image. Increased agglomeration of nano sized particles and improved crystallinity of the composite confirmed from Transmission electron microscopy (TEM) studies and selected area electron diffraction (SAED) pattern. The composite showed maximum sensing response of 4902 as against 183 of MF in the range 11%–97% RH. The response and recovery times of the composite were found to be 45 s and 74 s respectively while those of MF 225 s and 364 s respectively. The nanocomposite sample showed stable humidity sensing ability and a low humidity hysteresis. Molybdenum trioxide plays a major role in enhancing the humidity sensing performance of MFMO composite at room temperature. The sensing mechanism discussed on the basis of chemisorptions, physisorption and capillary condensation processes.</P> <P><B>Highlights</B></P> <P> <UL> <LI> Humidity sensing response of magnisium ferrite (MF) and magnesium ferrite-molybdenum trioxide (MFMO) composite presented. </LI> <LI> The MFMO showed maximum sensing response of 4902 as against 183 of MF in the range 11%-97% RH. </LI> <LI> The response and recovery times of the composite were found to be 45 s and 74 s respectively. </LI> <LI> The sensing mechanism MFMO discussed on the basis of chemisorptions, physisorption and capillary condensation processes. </LI> </UL> </P>