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        A high-resolution timescale for the Miocene Shanwang diatomaceous shale lagerstätte (China): development of Wavelet Scale Series Analysis for cyclostratigraphy

        Jifeng Yu,Xinlong Pang,Wenzhao Fu,Jason Hilton,Mingmei Liang,Zongkai Jiang,Xiuli Zhao,Wenyan Qiao,Suo Shi,Diandong Zhang,Huitao Cao,Haibo Jia,Yadong Wang,Xiaoke Hu,Rui Zhang 한국지질과학협의회 2021 Geosciences Journal Vol.25 No.5

        The Miocene aged Shanwang Formation from the Shanwang National Geopark in China represents a succession of lacustrine diatomaceous shales containing an abundant and diverse biota with lagerstätte fossilization of soft tissues. To date, the Shanwang Formation has not been investigated for cyclostratigraphy nor has it been dated with high precision methods. Now we use thorium data as a paleoenvironmental and paleoclimatic proxy to conduct a detailed cyclostratigraphic analysis. A new and simple cyclostratigraphic method, Wavelet Scale Series Analysis (WSSA) is developed to recognize Milankovitch cycles. A total of three short eccentricity and fifteen precession cycles are identified; obliquity cycles are not apparent. In the sedimentary succession, the corresponding precession and short eccentricity cycles are 1.17 m and 4.98 m thick respectively, with this verified by Correlation Coefficient (COCO) analysis and Multitaper-Method (MTM) spectral analysis. We estimate the studied interval was deposited over a duration of 0.3 Myr with a depositional rate of c. 5.7 cm/kyr. Paleomagnetic and radio isotope dating data shows that the diatomaceous shale was deposited during Chron C5En, which places it at approximately 18.5 Ma during the Burdigalian stage of the Early Miocene, rather than in the Middle Miocene as previously thought. The Shanwang lagerstätte biota therefore predates the Middle Miocene Climate Optimum (MMCO) and did not form within it. The geological time scale with a high resolution of 20 kyr was set accordingly.

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        Mechanisms of dry flue-gas desulfurization using natural manganese oxide ores

        Yongxiang Chen,Yunjiao LI,Xinlong Cao,Jianguo Li,Sanchuan Tang,Wanqi Ye,Xianzhen Zhang 한국화학공학회 2019 Korean Journal of Chemical Engineering Vol.36 No.7

        The mechanisms of flue-gas desulfurization using high and low-grade natural manganese oxide ores were comparatively studied. Both manganese oxide ores exhibit good desulfurization capabilities with SO2 content in the effluents less than 30 ppm, but the low-grade ores show the much better desulfurization capability. XRD and SEM/EDS results reveal that the MnO2 absorbs the SO2 to convert to MnSO4. The SO2 give prior to react with the surface MnO2 and the produced MnSO2 enriched on the surface leads to the gradually decrease of the SO2 removal rate during desulfurization process. The better desulfurization capability of the low-grade ores is ascribed to the more dispersive MnO2 due to the poriferous/lax internal tunnel structure, and the embedded inert SiO2 shows better support effects to avoid pore structure blocking, which is favorable for enhancing the diffusion of the SO2 and desulfurization reaction process. This study is of significance in the comprehensive utilization of the low-grade natural manganese oxide ores, environmental protection and even the preparation of the desulfurization catalyst with MnO2.

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