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Parviz Sukhrobov,Sodik Numonov,Sanshuang Gao,Xamxikamar Mamat,Thomas Wagberg,Yufen Guo,Liwei Liu,Guangzhi Hu 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.7
This study describes a type of novel nickel nanoparticles (NiNPs) decorated on Nafion-graphene composite film by using the electrochemical deposition method. It was used to fabricate electrochemical biosensors for sensitive nonenzymatic glucose detection. Compared with the Nafion–graphene film and NiNPs-modified glassy carbon electrode (NiNPs-GCE), the NiNPs/Nafion/graphene/GCE showed the best electrocatalytic activity towards glucose oxidation in alkaline medium. The NiNPs/Nafion/graphene/GCE at an applied potential of +0.55V in a linear range of 1–200 μM presented a high sensitivity of 3437.25 μA·mM -1 cm -2 with coefficient of correlation R2 = 0.999; and in a linear range of 200–10 800 μM it performed the best sensitivity of 2848.6 μA·mM -1 cm -2 with coefficient of correlation R2 = 0.995 towards glucose oxidation. For a concentration up to 200 M, a linear range was obtained with a limit of detection of 0.6 μM (signal to noise = 3) and as much as 10 800 μM with a limit of detection of 0.82 μM (signal to noise = 3). The time of responses was about 1–1.5 s with the addition of 0.1–1mM glucose. In addition, NiNPs/Nafion/graphene/GCE also has a high anti-interference ability toward common oxidative interfering species, such as uric acid, ascorbic acid and dopamine. More importantly, NiNPs/Nafion/graphene/GCE was successfully used for the determination of glucose concentration in human serum samples in comparison with a local hospital. The NiNPs/Nafion/graphene/GCE exhibited high sensitivity, low working potential, good stability, excellent electrical properties, enhanced selectivity and fast amperometric responses to glucose oxidation. Thus, as a nonenzymatic sensor, it is promising for future glucose determination development.
Ruyuan Jiang,Niantao Liu,Yuhong Su,Sanshuang Gao,Xamxikamar Mamat,Thomas Wågberg,Yongtao Li,Xun Hu,Guangzhi Hu 성균관대학교(자연과학캠퍼스) 성균나노과학기술원 2018 NANO Vol.13 No.08
An integrative electroanalytical method was developed for detecting Cd2+ and Pb2+ ions in aqueous solutions. Polysulfide/graphene (RGO-S) nanocomposites were prepared and their performance as electrochemical sensors for Cd2+ and Pb2+ was evaluated. The RGO-S nanocomposite was carefully characterized by scanning electron microscopy with energy-dispersive X-ray spectrometry, transmission electron microscopy, and X-ray photoelectron spectroscopy. The as-prepared RGO-S was incorporated into a pyrolytic graphite electrode (RGO-S/PGE) and used for detecting trace amount of Cd2+ and Pb2+ by differential pulse anodic stripping voltammetry. Under optimal conditions, the stripping peak current of RGO-S/PGE varies linearly with heavy metal ion concentration in the ranges 2.0–300 μg L -1 for Cd2+ and 1.0–300 μg L -1 for Pb2+. The limits of detection for Cd2+ and Pb2+ were estimated to be about 0.67 μg L -1 and 0.17 μg L -1, respectively. The prepared electrochemical heavy-metal-detecting electrode provides good repeatability and reproducibility with high sensitivity, making it a suitable candidate for monitoring Cd2+ and Pb2+ concentrations in aqueous environmental samples.