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Preparation and Hydrogen Barrier Property of FexAly/Al/Al2O3 Composite Coating on X80 Steel Surface
Bingying Wang,Xiaoyong Sun,Enyang Liu,Lin Liu,Wenjuan Ma,Yuze Shi,Peng Huang,Yun Luo 대한금속·재료학회 2024 METALS AND MATERIALS International Vol.30 No.1
Hydrogen-induced embrittlement is a significant safety concern for steel pipelines used in the transmission of hydrogenblendednatural gas. To mitigate this issue, hydrogen barrier coatings can be applied to the surface of steel substrates toreduce hydrogen permeation. In this study, rare earth oxides were optimized via first-principles calculations to identify themost effective doping agents. Subsequently, a FexAly/Al/Al2O3 composite coating doped with La2O3and Ce2O3was successfullyapplied to the surface of X80 steel using hot-dip aluminum plating combined with anodic oxidation. The coatingwas characterized using various techniques, including SEM, EDS, XRD, XPS, and hydrogen permeation tests. The resultsdemonstrated that co-doping La2O3and Ce2O3resulted in a lower adsorption energy of Al2O3to hydrogen molecules, andimproved the surface quality of the aluminizing layer and the composite coating. Electrochemical hydrogen permeationtests showed that the FexAly/Al/Al2O3 composite coating significantly improved the hydrogen barrier property of X80 steel. The anodizing current density was found to have a significant effect on the coating's morphology, which in turn affected thehydrogen barrier property of the coating. The composite coating obtained at an anodizing current density of 2 A/dm2 wasuniform and dense, without noticeable defects, and exhibited the best hydrogen barrier property.
Ken Chen,Shuhao Zhang,Duote Cai,Yuebin Zhang,Yi Jin,Wenjuan Luo,Zongwei Huang,Di Hu,Zhigang Gao 대한외과학회 2024 Annals of Surgical Treatment and Research(ASRT) Vol.106 No.4
Purpose: Whether a dilated intrahepatic bile duct (IHBD) has any effect on the prognosis of choledochal cyst (CC) remains controversial. We aimed to summarize the clinical characteristics and prognosis of CC with IHBD dilatation. Methods: One hundred ninety-two children diagnosed with CC were identified, including 127 without IHBD dilatation (group A) and 65 with IHBD dilatation (group B). A retrospective analysis was performed to explore the clinical characteristics and prognosis of CC with IHBD dilatation based on clinical indices, symptoms, and complications. Results: Compared with group A, incidences of jaundice and fever were higher in group B (P = 0.010 and P = 0.033). Preoperative total bilirubin, direct bilirubin, and indirect bilirubin were increased in group B compared to group A (P = 0.005, P < 0.001, and P = 0.014), as were preoperative ALT, AST, γ-GT, and total bile acid (P = 0.006, P = 0.025, P < 0.001, and P = 0.024). The risk of liver fibrosis or cirrhosis was significantly increased for group B compared with group A (P = 0.012) and also occurred earlier in group B (P = 0.006). In the dilated IHBDs, 95.4% (62 of 65) recovered to normal, and more than half of dilated IHBDs (37 of 65) recovered to normal in 1 week. Conclusion: Most IHBDs can recover to normal postoperatively in a short time, and proactive treatment is recommended for CC patients with IHBD dilatation for significant abnormal liver functions.