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      • Crystalline Phases and Dielectric Properties of Crystallized Glasses in the System (Ca, Sr, Ba) O-Al2O3-B2O3-SiO2-TiO2

        Tuzuku, Koichiro,Kishi, Hiroshi,Taruta, Seiichi,Takusagawa, Nobuo The Korean Ceramic Society 1999 The Korean journal of ceramics Vol.5 No.2

        Crystallization of glasses in the system (Ca, Sr, Ba)$O-Al_2O_3-B_2O_3-SiO_2-TiO_2$ and dielectric properties of crystallized glasses were investigated. As increasing B2O3 content and decreasing SiO2 content in the glass, the major crystalline phase changed from $(Sr, Ba)_2TiSi_2O_8$ to (Ca, Sr, Ba)TiO3, the dielectric constant of crystallized glasses increased and the Temperature Coefficient of Capacitance (TCC) changed to negative. The dielectric constant and TCC was estimated for (Sr, Ba)2TiSi2O8 phase as 18 and -440 $ppm/^{\circ}C$, respectively and for (Ca, Sr, Ba)TiO3 phase as 307 and -1900 $ppm/^{\circ}C$, respectively. The dielectric properties of (Ca, Sr, Ba)TiO3 phase (in this study) were similar to those of (Ca, Ba) TiO_3 solid-solution^12)$</TEXX>, but $(Sr, Ba)_2TiSi_2O_8$ phase (in this study) and $Sr_2TiSi_2O_\;8^4$ showed the different properties.

      • Sintering and Microstructure of Alumina/Mica and Spinel/Mica Composites

        Suzuki, Sofia-Saori,Taruta, Seiichi,Takusagawa, Nobuo The Korean Ceramic Society 1998 The Korean journal of ceramics Vol.4 No.4

        Alumina/mica and spinel/mica composites were fabricated by sintering of compacts containing 20 mass% fluoromica ($KMg_3AlSi_3O-{10}F_2$) glass and alumina or spinel. In both composites, mica precipitated as plate-like crystals at temperatures lower than $1300^{\circ}C$ and melted at $1300^{\circ}C$ to $1400^{\circ}C$. In alumina/mica composites, alumina and glass reacted to produce spinel, and the densification progressed by the solution-precipitation of alumina. Consequently, the glass composition changed and the mica did not precipitate at temperatures higher than $1400^{\circ}C$. However, mica precipitated after a reheating process. In spinel/mica composites, the glass composition did not change. After the mica phase melted, it recrystallized during slow cooling. The relative density reached the maximum at $1500^{\circ}C$ for alumina/mica and at $1300^{\circ}C$ spinel/mica composites, and decreased at further high temperatures.

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