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Metal-organic and porous organic framework in electrocatalytic water splitting
Sivalingam Gopi,Murugavel Kathiresan,Kyusik Yun 한국공업화학회 2023 Journal of Industrial and Engineering Chemistry Vol.126 No.-
The use of hydrogen as a clean and sustainable energy carrier is a desirable alternative to the use of fossilfuels. It is strongly anticipated that the development of superior electrocatalysts for boosting these processeswill reduce their overpotentials and increase the accessibility of their practical applications. Metalorganicframeworks (MOFs) and Porous organic polymers (POPs) are gaining popularity as nonpreciousalternatives to drive global water splitting due to their adaptable compositions, exceptional porosities,and ultrahigh surface areas. The use of metal–organic frameworks (MOFs) for electrochemical watersplitting has advanced rapidly in recent years. This article highlights the most significant findings fromrecent studies on designing advanced MOFs for enhancing electrochemical water splitting. Electrocatalysts based on metal–organic frameworks (MOFs) and Porous organic polymers (POPs) getspecial consideration with regard to their structure–property relationships, production methods, anddesign principles. We anticipate that this study will be a valuable tool for advancing the developmentof MOF and POP-based electrocatalysts towards usable water splitting and will also offer insights intopotential future energy technologies beyond water electrolysis.