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        Gelation Modification of Alginate Nonwoven Fabrics

        Jie Liu,Yun Liu,Dagang Miao,Shuying Sui,Chuanjie Zhang,Ping Zhu 한국섬유공학회 2018 Fibers and polymers Vol.19 No.8

        Calcium alginate nonwoven fabrics were gelation-modified by two-stage with aqueous HCl solution and then ethanolic NaOH solution. The structure and crystallinity properties of the samples were characterized by FT-IR, SEM, and XRD. The preparation conditions and modification mechanism were investigated. The results indicated that the crystal structure of calcium alginate fibers was destroyed; the crystallinity and calcium ion content decreased after HCl treatment. This resulted from the formation of ester bonds among the hydrolytic molecules after NaOH treatment. The best gel performance was obtained at the HCl concentration of 0.05-0.1 wt% with the NaOH concentration in ethanol of 2-4 mol/l. The liquid absorption of nonwoven alginate fabrics increased by 145 %. The water capability increased by 2673 % after modification, while the thickness, mass per unit area, permeability, and tensile strength of nonwoven alginate fabrics changed little.

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        The Effect of HPMC and CNC on the Structure and Properties of Alginate Fibers

        Meiyu Ci,Jie Liu,Shenglong Shang,Zhiming Jiang,Ping Zhu,Shuying Sui 한국섬유공학회 2020 Fibers and polymers Vol.21 No.10

        Bio-composite alginate fibers with binary and ternary blends were prepared by using cellulose nanocrystal (CNC)and hydroxypropyl methylcellulose (HPMC) as composite fillers through wet-spinning method. Structural, thermal,mechanical properties and surface morphology of fibers were characterized by Fourier transform infrared spectroscopy (FTIR),X-ray diffraction (XRD), Thermogravimetric Analysis (TGA), Mechanical strength testing, Scanning ElectronMicroscopy (SEM). The thermal stability and mechanical performance of SA/HPMC and SA/HPMC/CNC composite fibersimproved as the increasing of crystallinity and intermolecular H-bonding interaction of the fibers. HPMC is helpful toimprove the extensibility and stiffness of alginate fibers, and CNC can further enhance the stiffness of SA/HPMC compositefibers. The tensile strength, elongation at break, the initial modulus and work at break of SA/HPMC/CNC composite fiberswere superior to those of alginate fibers. Roughness of surface and tensile section of SA/HPMC and SA/HPMC/CNCcomposite fibers got increased. Water absorbency and salt resistance were significantly improved.

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